MOCVD precursor delivery monitored and controlled using UV spectroscopy

Brian J. Rappoli, William J. DeSisto, Tobin J Marks, John A. Belot

Research output: Contribution to journalArticle

Abstract

The glyme adducts of bis(1,1,1,5,5,5-hexafluoro-2,4-pentanedionate)barium, Ba(hfac)2·glyme, are frequently employed as precursors in the MOCVD fabrication of HTSC thin films. The physical properties of these precursors can be modified by changing the glyme ligand in the barium complex. In this study, gas phase concentrations of two barium complexes as a function of purge time and bubbler temperature have been examined by in-situ UV spectroscopy. Also presented are the details of a UV spectrophotometric-based feedback control system designed to maintain constant gas phase concentration of 2,2,6,6-tetramethyl-3,5-heptadionate (thd) precursors, Cu(thd)2 and Y(thd)3, during MOCVD growth of mixed metal oxide films.

Original languageEnglish
Pages (from-to)69-75
Number of pages7
JournalUnknown Journal
Volume477
Publication statusPublished - 1997

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Metallorganic chemical vapor deposition
Barium
Ultraviolet spectroscopy
Gases
Oxide films
Feedback control
Physical properties
Metals
Ligands
Control systems
Fabrication
Thin films
Temperature

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials

Cite this

Rappoli, B. J., DeSisto, W. J., Marks, T. J., & Belot, J. A. (1997). MOCVD precursor delivery monitored and controlled using UV spectroscopy. Unknown Journal, 477, 69-75.

MOCVD precursor delivery monitored and controlled using UV spectroscopy. / Rappoli, Brian J.; DeSisto, William J.; Marks, Tobin J; Belot, John A.

In: Unknown Journal, Vol. 477, 1997, p. 69-75.

Research output: Contribution to journalArticle

Rappoli, BJ, DeSisto, WJ, Marks, TJ & Belot, JA 1997, 'MOCVD precursor delivery monitored and controlled using UV spectroscopy', Unknown Journal, vol. 477, pp. 69-75.
Rappoli, Brian J. ; DeSisto, William J. ; Marks, Tobin J ; Belot, John A. / MOCVD precursor delivery monitored and controlled using UV spectroscopy. In: Unknown Journal. 1997 ; Vol. 477. pp. 69-75.
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