Models for organometallic molecule-support complexes. Very large counterion modulation of cationic actinide alkyl reactivity

Xinmin Yang, Charlotte L. Stern, Tobin J Marks

Research output: Contribution to journalArticle

253 Citations (Scopus)

Abstract

The reaction of Cp′2Th(CH3)2 (Cp′ = η5-(CH3)5C5) with HNnBu3+B(C6F5) 4- yields the crystallographically characterized, cationic thorium alkyl Cp′2ThCH3+B(C6F 5)4-. The B(C6F5)4- anion is weakly coordinated, the NMR spectroscopic parameters are similar to those of Cp′2Th(CH3)2 adsorbed on dehydroxylated alumina, and the complex is a highly active catalyst for ethylene polymerization and 1-hexene hydrogenation.

Original languageEnglish
Pages (from-to)840-842
Number of pages3
JournalOrganometallics
Volume10
Issue number4
Publication statusPublished - 1991

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry

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