Abstract
Methacrylamide polymers with pendant monodentate, bidentate, and tridentate phosphine ligands (poly-P1, poly-P2, and poly-P3, respectively) have been synthesized. These polymers react with Mo(N2)2(PPh2Me)4 to form polymers with bound molybdenum dinitrogen complexes. Similarly, MoCl3(THF)3 reacts with poly-P3 to form MoCl3(poly-P3). These polymers have been used to modify silicon and carbon electrodes. These electrodes have been characterized by cyclic voltammetry and FT-IR spectroscopy. The redox chemistry of electrodes modified with Mo(N2)2(poly-P3)PPh2Me and Mo(N2)2(poly-P2)2 on silicon and carbon electrodes closely parallels that observed for their solution counterparts. However, reduction of MoCl3(poly-P3) and MoCl3(poly-P2)2 on silicon and carbon electrodes does not lead to formation of polymer-bound molybdenum dinitrogen complexes.
| Original language | English |
|---|---|
| Pages (from-to) | 2047-2052 |
| Number of pages | 6 |
| Journal | Inorganic Chemistry |
| Volume | 23 |
| Issue number | 14 |
| Publication status | Published - 1984 |
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ASJC Scopus subject areas
- Inorganic Chemistry
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Modification of silicon and carbon electrodes with methacrylamide polymers containing covalently attached molybdenum dinitrogen complexes. / DuBois, Daniel L.
In: Inorganic Chemistry, Vol. 23, No. 14, 1984, p. 2047-2052.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Modification of silicon and carbon electrodes with methacrylamide polymers containing covalently attached molybdenum dinitrogen complexes
AU - DuBois, Daniel L
PY - 1984
Y1 - 1984
N2 - Methacrylamide polymers with pendant monodentate, bidentate, and tridentate phosphine ligands (poly-P1, poly-P2, and poly-P3, respectively) have been synthesized. These polymers react with Mo(N2)2(PPh2Me)4 to form polymers with bound molybdenum dinitrogen complexes. Similarly, MoCl3(THF)3 reacts with poly-P3 to form MoCl3(poly-P3). These polymers have been used to modify silicon and carbon electrodes. These electrodes have been characterized by cyclic voltammetry and FT-IR spectroscopy. The redox chemistry of electrodes modified with Mo(N2)2(poly-P3)PPh2Me and Mo(N2)2(poly-P2)2 on silicon and carbon electrodes closely parallels that observed for their solution counterparts. However, reduction of MoCl3(poly-P3) and MoCl3(poly-P2)2 on silicon and carbon electrodes does not lead to formation of polymer-bound molybdenum dinitrogen complexes.
AB - Methacrylamide polymers with pendant monodentate, bidentate, and tridentate phosphine ligands (poly-P1, poly-P2, and poly-P3, respectively) have been synthesized. These polymers react with Mo(N2)2(PPh2Me)4 to form polymers with bound molybdenum dinitrogen complexes. Similarly, MoCl3(THF)3 reacts with poly-P3 to form MoCl3(poly-P3). These polymers have been used to modify silicon and carbon electrodes. These electrodes have been characterized by cyclic voltammetry and FT-IR spectroscopy. The redox chemistry of electrodes modified with Mo(N2)2(poly-P3)PPh2Me and Mo(N2)2(poly-P2)2 on silicon and carbon electrodes closely parallels that observed for their solution counterparts. However, reduction of MoCl3(poly-P3) and MoCl3(poly-P2)2 on silicon and carbon electrodes does not lead to formation of polymer-bound molybdenum dinitrogen complexes.
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M3 - Article
VL - 23
SP - 2047
EP - 2052
JO - Inorganic Chemistry
JF - Inorganic Chemistry
SN - 0020-1669
IS - 14
ER -