Modulating the rate of charge transport in a metal-organic framework thin film using host:guest chemistry

Idan Hod, Omar K. Farha, Joseph T. Hupp

Research output: Contribution to journalArticle

34 Citations (Scopus)

Abstract

Herein we demonstrate the use of host-guest chemistry to modulate rates of charge transport in metal-organic framework (MOF) films. The kinetics of site-to-site of charge hopping and, in turn, the overall redox conductivity, of a ferrocene-modified MOF can be altered by up to 30-fold by coupling electron exchange to the oxidation-state-dependent formation of inclusion complexes between cyclodextrin and channel-tethered metallocenes.

Original languageEnglish
Pages (from-to)1705-1708
Number of pages4
JournalChemical Communications
Volume52
Issue number8
DOIs
Publication statusPublished - Jan 1 2016

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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