Abstract
Zirconium(iv)-containing metal-organic framework (MOF) catalysts NU-1000 and MOF-808 were compared to analogous catalysts synthesized by grafting the nodes onto bare and functionalized silica. As-synthesized, calcined, and activated catalysts all exhibit similar selectivity in the ring-opening of 1,2-epoxyoctane with isopropanol, but MOF-808 gives exceptionally high rates and yields per gram catalyst.
| Original language | English |
|---|---|
| Pages (from-to) | 6480-6484 |
| Number of pages | 5 |
| Journal | Catalysis Science and Technology |
| Volume | 6 |
| Issue number | 17 |
| DOIs | |
| Publication status | Published - 2016 |
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ASJC Scopus subject areas
- Catalysis
Cite this
MOFs and their grafted analogues : Regioselective epoxide ring-opening with Zr6 nodes. / Thornburg, Nicholas E.; Liu, Yangyang; Li, Peng; Hupp, Joseph T; Farha, Omar K.; Notestein, Justin M.
In: Catalysis Science and Technology, Vol. 6, No. 17, 2016, p. 6480-6484.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - MOFs and their grafted analogues
T2 - Regioselective epoxide ring-opening with Zr6 nodes
AU - Thornburg, Nicholas E.
AU - Liu, Yangyang
AU - Li, Peng
AU - Hupp, Joseph T
AU - Farha, Omar K.
AU - Notestein, Justin M
PY - 2016
Y1 - 2016
N2 - Zirconium(iv)-containing metal-organic framework (MOF) catalysts NU-1000 and MOF-808 were compared to analogous catalysts synthesized by grafting the nodes onto bare and functionalized silica. As-synthesized, calcined, and activated catalysts all exhibit similar selectivity in the ring-opening of 1,2-epoxyoctane with isopropanol, but MOF-808 gives exceptionally high rates and yields per gram catalyst.
AB - Zirconium(iv)-containing metal-organic framework (MOF) catalysts NU-1000 and MOF-808 were compared to analogous catalysts synthesized by grafting the nodes onto bare and functionalized silica. As-synthesized, calcined, and activated catalysts all exhibit similar selectivity in the ring-opening of 1,2-epoxyoctane with isopropanol, but MOF-808 gives exceptionally high rates and yields per gram catalyst.
UR - http://www.scopus.com/inward/record.url?scp=84983549731&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84983549731&partnerID=8YFLogxK
U2 - 10.1039/c6cy01093h
DO - 10.1039/c6cy01093h
M3 - Article
VL - 6
SP - 6480
EP - 6484
JO - Catalysis Science and Technology
JF - Catalysis Science and Technology
SN - 2044-4753
IS - 17
ER -