Abstract
The problem of resolving molecular components of the electronic structure of complex, organic solids with respect to their chemical and orbital character has been approached using soft X-ray absorption (SXA) and soft X-ray emission (SXE) spectroscopy. These techniques are powerful probes of the site and angular-momentum resolved partial density of states (PDOS) for both occupied and unoccupied states. Therefore these spectroscopies are particularly suited for an analysis of the density of states of multi-atomic, complex materials as the ET-based organic conductors, allowing site-specific electronic structure to be measured. We present a preliminary picture of the electronic structure of κ-ET2Cu(SCN)2 and κ-ET2Cu[N(CN)2]Br as measured by SXE and SXA performed at the C1s and N1s core levels.
Original language | English |
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Pages (from-to) | 539-544 |
Number of pages | 6 |
Journal | Journal of Electron Spectroscopy and Related Phenomena |
Volume | 101-103 |
DOIs | |
Publication status | Published - 1999 |
Keywords
- Density of states
- Organic conductors
- Soft X-ray emission spectroscopy
ASJC Scopus subject areas
- Electronic, Optical and Magnetic Materials
- Radiation
- Atomic and Molecular Physics, and Optics
- Condensed Matter Physics
- Spectroscopy
- Physical and Theoretical Chemistry