Molecular junctions: Can pulling influence optical controllability?

Shane M. Parker, Manuel Smeu, Ignacio Franco, Mark A. Ratner, Tamar Seideman

Research output: Contribution to journalArticle

17 Citations (Scopus)

Abstract

We suggest the combination of single molecule pulling and optical control as a way to enhance control over the electron transport characteristics of a molecular junction. We demonstrate using a model junction consisting of biphenyl-dithiol coupled to gold contacts. The junction is pulled while optically manipulating the dihedral angle between the two rings. Quantum dynamics simulations show that molecular pulling enhances the degree of control over the dihedral angle and hence over the transport properties.

Original languageEnglish
Pages (from-to)4587-4591
Number of pages5
JournalNano letters
Volume14
Issue number8
DOIs
Publication statusPublished - Aug 13 2014

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Keywords

  • Optical control
  • electron transport
  • molecular conductance
  • molecular junction
  • single-molecule pulling

ASJC Scopus subject areas

  • Bioengineering
  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanical Engineering

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