Molecular metals with widely tunable band filling structure/stoichiometry/counterion relationships in the electrochemistry of a cofacially joined polymeric phthalocyanine metal

John G. Gaudiello, Glen E. Kellogg, Stephen M. Tetrick, Tobin J Marks

Research output: Contribution to journalArticle

40 Citations (Scopus)

Abstract

The oxidative electrochemistry of the cofacially joined phthalocyanine polymer [Si(Pc)O]n to yield molecular metals/conductive polymers of the type {[Si(Pc)O]Xy}n is studied by a combination of X-ray diffractometric and spectroscopic techniques. Electrochemical methodology includes controlled-potential coulometry and electrochemical potential spectroscopy (ECPS) applied to rapidly stirred slurries or to microcompactions of the solid polymer. From the standpoint of electrically conductive polymers, this study illustrates the great sensitivity of electrochemical phenomena to polymer chain architecture (subunit packing, connectivity, geometry, electronic structure) and counterion structure. From the standpoint of molecular metals, the {[Si-(Pc)O]Xy}n systems represent the only system to date where wide tunability in band filling and counterion identity is possible.

Original languageEnglish
Pages (from-to)5259-5271
Number of pages13
JournalJournal of the American Chemical Society
Volume111
Issue number14
Publication statusPublished - Jul 5 1989

Fingerprint

Electrochemistry
Stoichiometry
Polymers
Metals
Coulometers
Slurries
Electronic structure
Spectrum Analysis
X-Rays
phthalocyanine
Spectroscopy
X rays
Geometry

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Molecular metals with widely tunable band filling structure/stoichiometry/counterion relationships in the electrochemistry of a cofacially joined polymeric phthalocyanine metal. / Gaudiello, John G.; Kellogg, Glen E.; Tetrick, Stephen M.; Marks, Tobin J.

In: Journal of the American Chemical Society, Vol. 111, No. 14, 05.07.1989, p. 5259-5271.

Research output: Contribution to journalArticle

@article{5005558bd2534348841299651622bc17,
title = "Molecular metals with widely tunable band filling structure/stoichiometry/counterion relationships in the electrochemistry of a cofacially joined polymeric phthalocyanine metal",
abstract = "The oxidative electrochemistry of the cofacially joined phthalocyanine polymer [Si(Pc)O]n to yield molecular metals/conductive polymers of the type {[Si(Pc)O]Xy}n is studied by a combination of X-ray diffractometric and spectroscopic techniques. Electrochemical methodology includes controlled-potential coulometry and electrochemical potential spectroscopy (ECPS) applied to rapidly stirred slurries or to microcompactions of the solid polymer. From the standpoint of electrically conductive polymers, this study illustrates the great sensitivity of electrochemical phenomena to polymer chain architecture (subunit packing, connectivity, geometry, electronic structure) and counterion structure. From the standpoint of molecular metals, the {[Si-(Pc)O]Xy}n systems represent the only system to date where wide tunability in band filling and counterion identity is possible.",
author = "Gaudiello, {John G.} and Kellogg, {Glen E.} and Tetrick, {Stephen M.} and Marks, {Tobin J}",
year = "1989",
month = "7",
day = "5",
language = "English",
volume = "111",
pages = "5259--5271",
journal = "Journal of the American Chemical Society",
issn = "0002-7863",
publisher = "American Chemical Society",
number = "14",

}

TY - JOUR

T1 - Molecular metals with widely tunable band filling structure/stoichiometry/counterion relationships in the electrochemistry of a cofacially joined polymeric phthalocyanine metal

AU - Gaudiello, John G.

AU - Kellogg, Glen E.

AU - Tetrick, Stephen M.

AU - Marks, Tobin J

PY - 1989/7/5

Y1 - 1989/7/5

N2 - The oxidative electrochemistry of the cofacially joined phthalocyanine polymer [Si(Pc)O]n to yield molecular metals/conductive polymers of the type {[Si(Pc)O]Xy}n is studied by a combination of X-ray diffractometric and spectroscopic techniques. Electrochemical methodology includes controlled-potential coulometry and electrochemical potential spectroscopy (ECPS) applied to rapidly stirred slurries or to microcompactions of the solid polymer. From the standpoint of electrically conductive polymers, this study illustrates the great sensitivity of electrochemical phenomena to polymer chain architecture (subunit packing, connectivity, geometry, electronic structure) and counterion structure. From the standpoint of molecular metals, the {[Si-(Pc)O]Xy}n systems represent the only system to date where wide tunability in band filling and counterion identity is possible.

AB - The oxidative electrochemistry of the cofacially joined phthalocyanine polymer [Si(Pc)O]n to yield molecular metals/conductive polymers of the type {[Si(Pc)O]Xy}n is studied by a combination of X-ray diffractometric and spectroscopic techniques. Electrochemical methodology includes controlled-potential coulometry and electrochemical potential spectroscopy (ECPS) applied to rapidly stirred slurries or to microcompactions of the solid polymer. From the standpoint of electrically conductive polymers, this study illustrates the great sensitivity of electrochemical phenomena to polymer chain architecture (subunit packing, connectivity, geometry, electronic structure) and counterion structure. From the standpoint of molecular metals, the {[Si-(Pc)O]Xy}n systems represent the only system to date where wide tunability in band filling and counterion identity is possible.

UR - http://www.scopus.com/inward/record.url?scp=0024962131&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0024962131&partnerID=8YFLogxK

M3 - Article

VL - 111

SP - 5259

EP - 5271

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

SN - 0002-7863

IS - 14

ER -