Molecular Oxygen as Oxidant in Heteropolyanion Catalysed Oxidations

Ronny Neumann; M. Levin

doi:10.1016/S0167-2991(08)62826-8

Molecular Oxygen as Oxidant in Heteropolyanion Catalysed Oxidations

Ronny Neumann, M. Levin

Weizmann Institute of Science, Israel

Research output: Contribution to journal › Article

15 Citations (Scopus)

Abstract

Molecular oxygen was used as the primary oxidant in transition metal substituted heteropolyanion, SiM(H₂O)W₁₁O₃₉ ^q-(M = Mn³⁺, Cu²⁺, Co²⁺, Fe³⁺), catalysed oxidative transformations of olefins in the presence of reducing agents. Product selectivity depended on the reductant used; thus in the presence of sodium dithionite allylic oxidation products were formed, collodial platinum and hydrogen catalysed epoxidation, and the use of sodium borohydride yielded saturated alcohols with both Markownikoff and anti-Markownikoff orientations.

Original language	English
Pages (from-to)	121-127
Number of pages	7
Journal	Studies in Surface Science and Catalysis
Volume	66
Issue number	C
DOIs	https://doi.org/10.1016/S0167-2991(08)62826-8
Publication status	Published - 1991

ASJC Scopus subject areas

Condensed Matter Physics
Catalysis
Physical and Theoretical Chemistry
Materials Chemistry
Surfaces, Coatings and Films

Access to Document

10.1016/S0167-2991(08)62826-8

Fingerprint Dive into the research topics of 'Molecular Oxygen as Oxidant in Heteropolyanion Catalysed Oxidations'. Together they form a unique fingerprint.

Cite this

Neumann, R., & Levin, M. (1991). Molecular Oxygen as Oxidant in Heteropolyanion Catalysed Oxidations. Studies in Surface Science and Catalysis, 66(C), 121-127. https://doi.org/10.1016/S0167-2991(08)62826-8

@article{cfebdb2424644b288fa0b6ecf2894afe,

title = "Molecular Oxygen as Oxidant in Heteropolyanion Catalysed Oxidations",

abstract = "Molecular oxygen was used as the primary oxidant in transition metal substituted heteropolyanion, SiM(H2O)W11O39 q-(M = Mn3+, Cu2+, Co2+, Fe3+), catalysed oxidative transformations of olefins in the presence of reducing agents. Product selectivity depended on the reductant used; thus in the presence of sodium dithionite allylic oxidation products were formed, collodial platinum and hydrogen catalysed epoxidation, and the use of sodium borohydride yielded saturated alcohols with both Markownikoff and anti-Markownikoff orientations.",

author = "Ronny Neumann and M. Levin",

year = "1991",

doi = "10.1016/S0167-2991(08)62826-8",

language = "English",

volume = "66",

pages = "121--127",

journal = "Studies in Surface Science and Catalysis",

issn = "0167-2991",

publisher = "Elsevier BV",

number = "C",

}

TY - JOUR

T1 - Molecular Oxygen as Oxidant in Heteropolyanion Catalysed Oxidations

AU - Neumann, Ronny

AU - Levin, M.

PY - 1991

Y1 - 1991

N2 - Molecular oxygen was used as the primary oxidant in transition metal substituted heteropolyanion, SiM(H2O)W11O39 q-(M = Mn3+, Cu2+, Co2+, Fe3+), catalysed oxidative transformations of olefins in the presence of reducing agents. Product selectivity depended on the reductant used; thus in the presence of sodium dithionite allylic oxidation products were formed, collodial platinum and hydrogen catalysed epoxidation, and the use of sodium borohydride yielded saturated alcohols with both Markownikoff and anti-Markownikoff orientations.

AB - Molecular oxygen was used as the primary oxidant in transition metal substituted heteropolyanion, SiM(H2O)W11O39 q-(M = Mn3+, Cu2+, Co2+, Fe3+), catalysed oxidative transformations of olefins in the presence of reducing agents. Product selectivity depended on the reductant used; thus in the presence of sodium dithionite allylic oxidation products were formed, collodial platinum and hydrogen catalysed epoxidation, and the use of sodium borohydride yielded saturated alcohols with both Markownikoff and anti-Markownikoff orientations.

UR - http://www.scopus.com/inward/record.url?scp=0011330489&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0011330489&partnerID=8YFLogxK

U2 - 10.1016/S0167-2991(08)62826-8

DO - 10.1016/S0167-2991(08)62826-8

M3 - Article

AN - SCOPUS:0011330489

VL - 66

SP - 121

EP - 127

JO - Studies in Surface Science and Catalysis

JF - Studies in Surface Science and Catalysis

SN - 0167-2991

IS - C

ER -