Abstract
Molecular oxygen was used as the primary oxidant in transition metal substituted heteropolyanion, SiM(H2O)W11O39 q-(M = Mn3+, Cu2+, Co2+, Fe3+), catalysed oxidative transformations of olefins in the presence of reducing agents. Product selectivity depended on the reductant used; thus in the presence of sodium dithionite allylic oxidation products were formed, collodial platinum and hydrogen catalysed epoxidation, and the use of sodium borohydride yielded saturated alcohols with both Markownikoff and anti-Markownikoff orientations.
| Original language | English |
|---|---|
| Pages (from-to) | 121-127 |
| Number of pages | 7 |
| Journal | Studies in Surface Science and Catalysis |
| Volume | 66 |
| Issue number | C |
| DOIs | |
| Publication status | Published - 1991 |
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ASJC Scopus subject areas
- Condensed Matter Physics
- Catalysis
- Physical and Theoretical Chemistry
- Materials Chemistry
- Surfaces, Coatings and Films
Cite this
Molecular Oxygen as Oxidant in Heteropolyanion Catalysed Oxidations. / Neumann, Ronny; Levin, M.
In: Studies in Surface Science and Catalysis, Vol. 66, No. C, 1991, p. 121-127.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Molecular Oxygen as Oxidant in Heteropolyanion Catalysed Oxidations
AU - Neumann, Ronny
AU - Levin, M.
PY - 1991
Y1 - 1991
N2 - Molecular oxygen was used as the primary oxidant in transition metal substituted heteropolyanion, SiM(H2O)W11O39 q-(M = Mn3+, Cu2+, Co2+, Fe3+), catalysed oxidative transformations of olefins in the presence of reducing agents. Product selectivity depended on the reductant used; thus in the presence of sodium dithionite allylic oxidation products were formed, collodial platinum and hydrogen catalysed epoxidation, and the use of sodium borohydride yielded saturated alcohols with both Markownikoff and anti-Markownikoff orientations.
AB - Molecular oxygen was used as the primary oxidant in transition metal substituted heteropolyanion, SiM(H2O)W11O39 q-(M = Mn3+, Cu2+, Co2+, Fe3+), catalysed oxidative transformations of olefins in the presence of reducing agents. Product selectivity depended on the reductant used; thus in the presence of sodium dithionite allylic oxidation products were formed, collodial platinum and hydrogen catalysed epoxidation, and the use of sodium borohydride yielded saturated alcohols with both Markownikoff and anti-Markownikoff orientations.
UR - http://www.scopus.com/inward/record.url?scp=0011330489&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0011330489&partnerID=8YFLogxK
U2 - 10.1016/S0167-2991(08)62826-8
DO - 10.1016/S0167-2991(08)62826-8
M3 - Article
VL - 66
SP - 121
EP - 127
JO - Studies in Surface Science and Catalysis
JF - Studies in Surface Science and Catalysis
SN - 0167-2991
IS - C
ER -