Molecular Oxygen as Oxidant in Heteropolyanion Catalysed Oxidations

Ronny Neumann, M. Levin

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

Molecular oxygen was used as the primary oxidant in transition metal substituted heteropolyanion, SiM(H2O)W11O39 q-(M = Mn3+, Cu2+, Co2+, Fe3+), catalysed oxidative transformations of olefins in the presence of reducing agents. Product selectivity depended on the reductant used; thus in the presence of sodium dithionite allylic oxidation products were formed, collodial platinum and hydrogen catalysed epoxidation, and the use of sodium borohydride yielded saturated alcohols with both Markownikoff and anti-Markownikoff orientations.

Original languageEnglish
Pages (from-to)121-127
Number of pages7
JournalStudies in Surface Science and Catalysis
Volume66
Issue numberC
DOIs
Publication statusPublished - 1991

Fingerprint

Molecular oxygen
Reducing Agents
Oxidants
Sodium
sodium
Dithionite
Oxidation
oxidation
epoxidation
Epoxidation
borohydrides
Alkenes
Reducing agents
oxygen
products
Platinum
alkenes
Olefins
Transition metals
Hydrogen

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Catalysis
  • Physical and Theoretical Chemistry
  • Materials Chemistry
  • Surfaces, Coatings and Films

Cite this

Molecular Oxygen as Oxidant in Heteropolyanion Catalysed Oxidations. / Neumann, Ronny; Levin, M.

In: Studies in Surface Science and Catalysis, Vol. 66, No. C, 1991, p. 121-127.

Research output: Contribution to journalArticle

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