Molecular recognition in homogeneous transition metal catalysis: A biomimetic strategy for high selectivity

Siddartha Das; Gary W. Brudvig; Robert H. Crabtree

doi:10.1039/b710355g

Molecular recognition in homogeneous transition metal catalysis: A biomimetic strategy for high selectivity

Siddartha Das, Gary W. Brudvig, Robert H. Crabtree

Yale University

Research output: Contribution to journal › Review article › peer-review

11 Citations (Scopus)

Abstract

Traditional methods for selectivity control in homogeneous transition metal catalysis either employ steric effects in a binding pocket or chelate control. In a supramolecular strategy, encapsulation of the substrate can provide useful shape and size selectivity. A fully developed molecular recognition strategy involving hydrogen bonding or solvophobic forces has given almost completely regioselective functionalization of remote, unactivated C-H bonds.

Original language	English
Pages (from-to)	413-424
Number of pages	12
Journal	Chemical Communications
Volume	8
Issue number	4
DOIs	https://doi.org/10.1039/b710355g
Publication status	Published - 2008

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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abstract = "Traditional methods for selectivity control in homogeneous transition metal catalysis either employ steric effects in a binding pocket or chelate control. In a supramolecular strategy, encapsulation of the substrate can provide useful shape and size selectivity. A fully developed molecular recognition strategy involving hydrogen bonding or solvophobic forces has given almost completely regioselective functionalization of remote, unactivated C-H bonds.",

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