Abstract
Traditional methods for selectivity control in homogeneous transition metal catalysis either employ steric effects in a binding pocket or chelate control. In a supramolecular strategy, encapsulation of the substrate can provide useful shape and size selectivity. A fully developed molecular recognition strategy involving hydrogen bonding or solvophobic forces has given almost completely regioselective functionalization of remote, unactivated C-H bonds.
| Original language | English |
|---|---|
| Pages (from-to) | 413-424 |
| Number of pages | 12 |
| Journal | Chemical Communications |
| Volume | 8 |
| Issue number | 4 |
| DOIs | |
| Publication status | Published - 2008 |
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ASJC Scopus subject areas
- Chemistry(all)
Cite this
Molecular recognition in homogeneous transition metal catalysis : A biomimetic strategy for high selectivity. / Das, Siddartha; Brudvig, Gary W; Crabtree, Robert H.
In: Chemical Communications, Vol. 8, No. 4, 2008, p. 413-424.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Molecular recognition in homogeneous transition metal catalysis
T2 - A biomimetic strategy for high selectivity
AU - Das, Siddartha
AU - Brudvig, Gary W
AU - Crabtree, Robert H.
PY - 2008
Y1 - 2008
N2 - Traditional methods for selectivity control in homogeneous transition metal catalysis either employ steric effects in a binding pocket or chelate control. In a supramolecular strategy, encapsulation of the substrate can provide useful shape and size selectivity. A fully developed molecular recognition strategy involving hydrogen bonding or solvophobic forces has given almost completely regioselective functionalization of remote, unactivated C-H bonds.
AB - Traditional methods for selectivity control in homogeneous transition metal catalysis either employ steric effects in a binding pocket or chelate control. In a supramolecular strategy, encapsulation of the substrate can provide useful shape and size selectivity. A fully developed molecular recognition strategy involving hydrogen bonding or solvophobic forces has given almost completely regioselective functionalization of remote, unactivated C-H bonds.
UR - http://www.scopus.com/inward/record.url?scp=38049155811&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=38049155811&partnerID=8YFLogxK
U2 - 10.1039/b710355g
DO - 10.1039/b710355g
M3 - Article
AN - SCOPUS:38049155811
VL - 8
SP - 413
EP - 424
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 4
ER -