Abstract
Self-limiting siloxane chemisorptive self-assembly approaches have been employed to construct multilayer organic LED (OLED) structures. Extensive characterization of the deposition of a prototype triaryamine hole transport layer precursor on ITO using ellipsometry, X-ray reflectivity, AFM, XPS, and cyclic voltammetry reveal that smooth, contiguous, pinhole-free multilayer structures can be sequentially built up angstrom-level precision. Vapor deposition of a conventional emissive/electron transport layer and a metal electrode on the self-assembled HTL structure yields stable OLED structures with low turn-on voltages, high light output, and good external quantum efficiencies. Finally, self-assembly of an emissive layer on an ITO/HTL structure, followed by a LiF buffer layer and metal electrode, affords the first totally self-assembled two-layer OLED devices which emit continuous blue light.
| Original language | English |
|---|---|
| Title of host publication | American Chemical Society, Polymer Preprints, Division of Polymer Chemistry |
| Editors | Anon |
| Publisher | ACS |
| Pages | 1083-1084 |
| Number of pages | 2 |
| Volume | 39 |
| Edition | 2 |
| Publication status | Published - Aug 1998 |
| Event | Proceedings of the 1997 Boston Meeting - Boston, MA, USA Duration: Aug 23 1998 → Aug 27 1998 |
Other
| Other | Proceedings of the 1997 Boston Meeting |
|---|---|
| City | Boston, MA, USA |
| Period | 8/23/98 → 8/27/98 |
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ASJC Scopus subject areas
- Polymers and Plastics
Cite this
Molecular self-assembly routes to electroluminescent multilayer structures. / Li, Weijin; Malinsky, Joshua E.; Chou, Homer; Ma, Wuping; Geng, Lifeng; Marks, Tobin J; Jabbour, Ghassan E.; Shaheen, Sean E.; Kippelen, Bernard; Peyghambarian, Nasser; Dutta, Pulak; Richter, Andrew G.; Armstrong, Neal R.; Lee, Paul A.; Anderson, Jeffrey D.
American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. ed. / Anon. Vol. 39 2. ed. ACS, 1998. p. 1083-1084.Research output: Chapter in Book/Report/Conference proceeding › Conference contribution
}
TY - GEN
T1 - Molecular self-assembly routes to electroluminescent multilayer structures
AU - Li, Weijin
AU - Malinsky, Joshua E.
AU - Chou, Homer
AU - Ma, Wuping
AU - Geng, Lifeng
AU - Marks, Tobin J
AU - Jabbour, Ghassan E.
AU - Shaheen, Sean E.
AU - Kippelen, Bernard
AU - Peyghambarian, Nasser
AU - Dutta, Pulak
AU - Richter, Andrew G.
AU - Armstrong, Neal R.
AU - Lee, Paul A.
AU - Anderson, Jeffrey D.
PY - 1998/8
Y1 - 1998/8
N2 - Self-limiting siloxane chemisorptive self-assembly approaches have been employed to construct multilayer organic LED (OLED) structures. Extensive characterization of the deposition of a prototype triaryamine hole transport layer precursor on ITO using ellipsometry, X-ray reflectivity, AFM, XPS, and cyclic voltammetry reveal that smooth, contiguous, pinhole-free multilayer structures can be sequentially built up angstrom-level precision. Vapor deposition of a conventional emissive/electron transport layer and a metal electrode on the self-assembled HTL structure yields stable OLED structures with low turn-on voltages, high light output, and good external quantum efficiencies. Finally, self-assembly of an emissive layer on an ITO/HTL structure, followed by a LiF buffer layer and metal electrode, affords the first totally self-assembled two-layer OLED devices which emit continuous blue light.
AB - Self-limiting siloxane chemisorptive self-assembly approaches have been employed to construct multilayer organic LED (OLED) structures. Extensive characterization of the deposition of a prototype triaryamine hole transport layer precursor on ITO using ellipsometry, X-ray reflectivity, AFM, XPS, and cyclic voltammetry reveal that smooth, contiguous, pinhole-free multilayer structures can be sequentially built up angstrom-level precision. Vapor deposition of a conventional emissive/electron transport layer and a metal electrode on the self-assembled HTL structure yields stable OLED structures with low turn-on voltages, high light output, and good external quantum efficiencies. Finally, self-assembly of an emissive layer on an ITO/HTL structure, followed by a LiF buffer layer and metal electrode, affords the first totally self-assembled two-layer OLED devices which emit continuous blue light.
UR - http://www.scopus.com/inward/record.url?scp=0032139549&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0032139549&partnerID=8YFLogxK
M3 - Conference contribution
VL - 39
SP - 1083
EP - 1084
BT - American Chemical Society, Polymer Preprints, Division of Polymer Chemistry
A2 - Anon, null
PB - ACS
ER -