Molecular wire junctions: Tuning the conductance

Vladimiro Mujica, Abraham Nitzan, Supriyo Datta, Mark A Ratner, C. P. Kubiak

Research output: Contribution to journalArticle

53 Citations (Scopus)

Abstract

Junctions consisting of two electrodes and a single molecule acting as a wire can be investigated by scanning probe conductance measurements. The conductance for low temperature, short wire structures can be characterized by the elastic scattering of the electrons, as described by general Landauer formulas. Tuning the bridge energy levels either by field effect transistor (FET)-like behavior (charging) or by chemical bond formation can raise or lower the conductance by moving the poles of the molecular Green's function. For small molecular structures with particular HOMO/LUMO characteristics, functionalization might be a more effective means than Coulomb charging by external gates.

Original languageEnglish
Pages (from-to)91-95
Number of pages5
JournalJournal of Physical Chemistry B
Volume107
Issue number1
DOIs
Publication statusPublished - Jan 9 2003

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Tuning
tuning
wire
Wire
Elastic scattering
charging
Chemical bonds
Field effect transistors
Green's function
Electron energy levels
Molecular structure
Poles
chemical bonds
Scanning
Electrodes
Molecules
Electrons
elastic scattering
molecular structure
poles

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

Cite this

Molecular wire junctions : Tuning the conductance. / Mujica, Vladimiro; Nitzan, Abraham; Datta, Supriyo; Ratner, Mark A; Kubiak, C. P.

In: Journal of Physical Chemistry B, Vol. 107, No. 1, 09.01.2003, p. 91-95.

Research output: Contribution to journalArticle

Mujica, Vladimiro ; Nitzan, Abraham ; Datta, Supriyo ; Ratner, Mark A ; Kubiak, C. P. / Molecular wire junctions : Tuning the conductance. In: Journal of Physical Chemistry B. 2003 ; Vol. 107, No. 1. pp. 91-95.
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