Molecular wires

Extended coupling and disorder effects

Mathieu Kemp, Adrian Roitberg, Vladimiro Mujica, Todd Wanta, Mark A Ratner

Research output: Contribution to journalArticle

104 Citations (Scopus)

Abstract

Molecular wires are studied with respect to disorder and to increased electronic connectivity. We find that, with increased connectivity, the tendency to exhibit sharp changes of the conductance with modifications of the bridge structure is reduced. We find that the conductance falls off exponentially with distance for injection energies below the bridge energy band, and shows quantum behavior (oscillatory with wire length) for injection in the band. With disorder, we find that the distribution of conductances is lognormal, the parameters of which depend on disorder and on connectivity.

Original languageEnglish
Pages (from-to)8349-8355
Number of pages7
JournalJournal of Physical Chemistry
Volume100
Issue number20
Publication statusPublished - May 16 1996

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wire
Wire
disorders
Band structure
injection
bridges (structures)
energy bands
tendencies
electronics
energy

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Engineering(all)

Cite this

Molecular wires : Extended coupling and disorder effects. / Kemp, Mathieu; Roitberg, Adrian; Mujica, Vladimiro; Wanta, Todd; Ratner, Mark A.

In: Journal of Physical Chemistry, Vol. 100, No. 20, 16.05.1996, p. 8349-8355.

Research output: Contribution to journalArticle

Kemp, M, Roitberg, A, Mujica, V, Wanta, T & Ratner, MA 1996, 'Molecular wires: Extended coupling and disorder effects', Journal of Physical Chemistry, vol. 100, no. 20, pp. 8349-8355.
Kemp, Mathieu ; Roitberg, Adrian ; Mujica, Vladimiro ; Wanta, Todd ; Ratner, Mark A. / Molecular wires : Extended coupling and disorder effects. In: Journal of Physical Chemistry. 1996 ; Vol. 100, No. 20. pp. 8349-8355.
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