Molten Ga as a solvent for exploratory synthesis: The new ternary polygallide Sm2NiGa12

X. Z. Chen; P. Small; S. Sportouch; M. Zhuravleva; P. Brazis; C. R. Kannewurf; M. G. Kanatzidis

doi:10.1021/cm0002261

Molten Ga as a solvent for exploratory synthesis: The new ternary polygallide Sm₂NiGa₁₂

X. Z. Chen, P. Small, S. Sportouch, M. Zhuravleva, P. Brazis, C. R. Kannewurf, M. G. Kanatzidis

Northwestern University

Research output: Contribution to journal › Article

40 Citations (Scopus)

Abstract

Molten Ga is an excellent solvent for the preparation of the polygallide Sm₂NiGa₁₂. The compound is metallic and adopts an unusual three-dimensional structure composed of two different kinds of alternating segments. One segment has Ni and Ga atoms and is reminiscent of the KCu₄S₃ structure type. The other has only Ga atoms and adopts an elaborate Ga network.

Original language	English
Pages (from-to)	2520-2522
Number of pages	3
Journal	Chemistry of Materials
Volume	12
Issue number	9
DOIs	https://doi.org/10.1021/cm0002261
Publication status	Published - Oct 21 2000

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ASJC Scopus subject areas

Chemistry(all)
Chemical Engineering(all)
Materials Chemistry

Cite this

Chen, X. Z., Small, P., Sportouch, S., Zhuravleva, M., Brazis, P., Kannewurf, C. R., & Kanatzidis, M. G. (2000). Molten Ga as a solvent for exploratory synthesis: The new ternary polygallide Sm₂NiGa₁₂. Chemistry of Materials, 12(9), 2520-2522. https://doi.org/10.1021/cm0002261

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Access to Document

10.1021/cm0002261