Molten Ga as a solvent for exploratory synthesis: The new ternary polygallide Sm2NiGa12

X. Z. Chen, P. Small, S. Sportouch, M. Zhuravleva, P. Brazis, C. R. Kannewurf, M. G. Kanatzidis

Research output: Contribution to journalArticle

40 Citations (Scopus)

Abstract

Molten Ga is an excellent solvent for the preparation of the polygallide Sm2NiGa12. The compound is metallic and adopts an unusual three-dimensional structure composed of two different kinds of alternating segments. One segment has Ni and Ga atoms and is reminiscent of the KCu4S3 structure type. The other has only Ga atoms and adopts an elaborate Ga network.

Original languageEnglish
Pages (from-to)2520-2522
Number of pages3
JournalChemistry of Materials
Volume12
Issue number9
DOIs
Publication statusPublished - Oct 21 2000

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)
  • Materials Chemistry

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    Chen, X. Z., Small, P., Sportouch, S., Zhuravleva, M., Brazis, P., Kannewurf, C. R., & Kanatzidis, M. G. (2000). Molten Ga as a solvent for exploratory synthesis: The new ternary polygallide Sm2NiGa12. Chemistry of Materials, 12(9), 2520-2522. https://doi.org/10.1021/cm0002261