Molten Ga as a solvent for exploratory synthesis: The new ternary polygallide Sm2NiGa12

X. Z. Chen; P. Small; S. Sportouch; M. Zhuravleva; P. Brazis; C. R. Kannewurf; M. G. Kanatzidis

doi:10.1021/cm0002261

Molten Ga as a solvent for exploratory synthesis: The new ternary polygallide Sm₂NiGa₁₂

X. Z. Chen, P. Small, S. Sportouch, M. Zhuravleva, P. Brazis, C. R. Kannewurf, M. G. Kanatzidis

Northwestern University

Research output: Contribution to journal › Article › peer-review

40 Citations (Scopus)

Abstract

Molten Ga is an excellent solvent for the preparation of the polygallide Sm₂NiGa₁₂. The compound is metallic and adopts an unusual three-dimensional structure composed of two different kinds of alternating segments. One segment has Ni and Ga atoms and is reminiscent of the KCu₄S₃ structure type. The other has only Ga atoms and adopts an elaborate Ga network.

Original language	English
Pages (from-to)	2520-2522
Number of pages	3
Journal	Chemistry of Materials
Volume	12
Issue number	9
DOIs	https://doi.org/10.1021/cm0002261
Publication status	Published - Oct 21 2000

ASJC Scopus subject areas

Chemistry(all)
Chemical Engineering(all)
Materials Chemistry

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AU - Brazis, P.

AU - Kannewurf, C. R.

AU - Kanatzidis, M. G.

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AB - Molten Ga is an excellent solvent for the preparation of the polygallide Sm2NiGa12. The compound is metallic and adopts an unusual three-dimensional structure composed of two different kinds of alternating segments. One segment has Ni and Ga atoms and is reminiscent of the KCu4S3 structure type. The other has only Ga atoms and adopts an elaborate Ga network.

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