MULTIPLET SPLITTING OF CORE-ELECTRON BINDING ENERGIES IN TRANSITION-METAL IONS

CS FADLEY CS, DA SHIRLEY DA, Arthur J Freeman, PS BAGUS PS, JW MALLOW JW

Research output: Contribution to journalArticle

248 Citations (Scopus)

Abstract

Xray photoelectron spectra indicate core-electron binding- energy splittings of about 6 ev for the 3 s levels in MnF//2, MnO, and FeF//3, and less pronounced effects on the 3s levels in MnO//2 and Fe metal. Thes e splittings are considerably reduced from free-ion predictions but agree well with calculations for Mn in a cluster environment. The sp multiplet splittings are shown to behave in a quantitatively different fashion.

Original languageEnglish
Pages (from-to)1397-1401
Number of pages5
JournalPhysical Review Letters
Volume23
Issue number24
DOIs
Publication statusPublished - Jan 1 1969

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metal ions
binding energy
fine structure
transition metals
electrons
photoelectrons
predictions
metals
ions

ASJC Scopus subject areas

  • Physics and Astronomy(all)

Cite this

MULTIPLET SPLITTING OF CORE-ELECTRON BINDING ENERGIES IN TRANSITION-METAL IONS. / FADLEY CS, CS; SHIRLEY DA, DA; Freeman, Arthur J; BAGUS PS, PS; MALLOW JW, JW.

In: Physical Review Letters, Vol. 23, No. 24, 01.01.1969, p. 1397-1401.

Research output: Contribution to journalArticle

FADLEY CS, CS ; SHIRLEY DA, DA ; Freeman, Arthur J ; BAGUS PS, PS ; MALLOW JW, JW. / MULTIPLET SPLITTING OF CORE-ELECTRON BINDING ENERGIES IN TRANSITION-METAL IONS. In: Physical Review Letters. 1969 ; Vol. 23, No. 24. pp. 1397-1401.
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