N- and P-Type Building Blocks for Organic Electronics Based on Oligothiophene Cores

Antonio Facchetti, Myung Han Yoon, Howard E. Katz, Melissa Mushrush, Tobin J Marks

Research output: Chapter in Book/Report/Conference proceedingConference contribution

4 Citations (Scopus)

Abstract

Organic semiconductors exhibiting complementary-type carrier mobility are the key components for the development of the field of "plastic electronics". We present here a novel series of α,ω- and isomerically pure β,β'-diperfluorohexyl-substituted thiophene and study the impact of fluoroalkyl substitution and conjugation length vìs-à-vìs the corresponding fluorine-free analogues. Trends between the fluorinated and fluorine-free families in molecular packing, HOMO-LUMO gap, and π-π interactions are found to be strikingly similar. TFT measurements indicate that all members of the fluorinated series are n-type semiconductors.

Original languageEnglish
Title of host publicationMaterials Research Society Symposium - Proceedings
EditorsN. Fruehauf, B.E. Gnade, J. Jang
Pages375-380
Number of pages6
Volume769
Publication statusPublished - 2003
EventFlexible Electronics - Materials and Device Technology - San Francisco, CA, United States
Duration: Apr 22 2003Apr 25 2003

Other

OtherFlexible Electronics - Materials and Device Technology
CountryUnited States
CitySan Francisco, CA
Period4/22/034/25/03

Fingerprint

Fluorine
Electronic equipment
Thiophenes
Semiconducting organic compounds
Carrier mobility
Thiophene
Substitution reactions
Semiconductor materials
Plastics

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials

Cite this

Facchetti, A., Yoon, M. H., Katz, H. E., Mushrush, M., & Marks, T. J. (2003). N- and P-Type Building Blocks for Organic Electronics Based on Oligothiophene Cores. In N. Fruehauf, B. E. Gnade, & J. Jang (Eds.), Materials Research Society Symposium - Proceedings (Vol. 769, pp. 375-380)

N- and P-Type Building Blocks for Organic Electronics Based on Oligothiophene Cores. / Facchetti, Antonio; Yoon, Myung Han; Katz, Howard E.; Mushrush, Melissa; Marks, Tobin J.

Materials Research Society Symposium - Proceedings. ed. / N. Fruehauf; B.E. Gnade; J. Jang. Vol. 769 2003. p. 375-380.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Facchetti, A, Yoon, MH, Katz, HE, Mushrush, M & Marks, TJ 2003, N- and P-Type Building Blocks for Organic Electronics Based on Oligothiophene Cores. in N Fruehauf, BE Gnade & J Jang (eds), Materials Research Society Symposium - Proceedings. vol. 769, pp. 375-380, Flexible Electronics - Materials and Device Technology, San Francisco, CA, United States, 4/22/03.
Facchetti A, Yoon MH, Katz HE, Mushrush M, Marks TJ. N- and P-Type Building Blocks for Organic Electronics Based on Oligothiophene Cores. In Fruehauf N, Gnade BE, Jang J, editors, Materials Research Society Symposium - Proceedings. Vol. 769. 2003. p. 375-380
Facchetti, Antonio ; Yoon, Myung Han ; Katz, Howard E. ; Mushrush, Melissa ; Marks, Tobin J. / N- and P-Type Building Blocks for Organic Electronics Based on Oligothiophene Cores. Materials Research Society Symposium - Proceedings. editor / N. Fruehauf ; B.E. Gnade ; J. Jang. Vol. 769 2003. pp. 375-380
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