N- and P-Type Building Blocks for Organic Electronics Based on Ollgothiophene Cores

Antonio Facchetti, Myung Han Yoon, Howard E. Katz, Melissa Mushiush, Tobin J Marks

Research output: Chapter in Book/Report/Conference proceedingConference contribution

3 Citations (Scopus)

Abstract

Organic semiconductors exhibiting complementary-type carrier mobility are the key components for the development of the field of "plastic electronics". We present here a novel series of α,ω- and isomerically pure β,β′-diperfluorohexyl-substituted thiophene and study the impact of fluoroalkyl substitution and conjugation length vìs-à-vìs the corresponding fluorine-free analogues. Trends between the fluorinated and fluorine-free families in molecular packing, HOMO-LUMO gap, and π-π interactions are found to be strikingly similar. TFT measurements indicate that all members of the fluorinated series are n-type semiconductors.

Original languageEnglish
Title of host publicationMaterials Research Society Symposium - Proceedings
EditorsP.W.M. Blom, N.C. Greenham, C.D. Dimitrakopoulos, C.D. Frisbie
Pages397-402
Number of pages6
Volume771
Publication statusPublished - 2003
EventOrganic and Polymeric Materials and Devices - San Francisco, CA, United States
Duration: Apr 22 2003Apr 25 2003

Other

OtherOrganic and Polymeric Materials and Devices
CountryUnited States
CitySan Francisco, CA
Period4/22/034/25/03

Fingerprint

Fluorine
Electronic equipment
Thiophenes
Semiconducting organic compounds
Carrier mobility
Thiophene
Substitution reactions
Semiconductor materials
Plastics

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials

Cite this

Facchetti, A., Yoon, M. H., Katz, H. E., Mushiush, M., & Marks, T. J. (2003). N- and P-Type Building Blocks for Organic Electronics Based on Ollgothiophene Cores. In P. W. M. Blom, N. C. Greenham, C. D. Dimitrakopoulos, & C. D. Frisbie (Eds.), Materials Research Society Symposium - Proceedings (Vol. 771, pp. 397-402)

N- and P-Type Building Blocks for Organic Electronics Based on Ollgothiophene Cores. / Facchetti, Antonio; Yoon, Myung Han; Katz, Howard E.; Mushiush, Melissa; Marks, Tobin J.

Materials Research Society Symposium - Proceedings. ed. / P.W.M. Blom; N.C. Greenham; C.D. Dimitrakopoulos; C.D. Frisbie. Vol. 771 2003. p. 397-402.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Facchetti, A, Yoon, MH, Katz, HE, Mushiush, M & Marks, TJ 2003, N- and P-Type Building Blocks for Organic Electronics Based on Ollgothiophene Cores. in PWM Blom, NC Greenham, CD Dimitrakopoulos & CD Frisbie (eds), Materials Research Society Symposium - Proceedings. vol. 771, pp. 397-402, Organic and Polymeric Materials and Devices, San Francisco, CA, United States, 4/22/03.
Facchetti A, Yoon MH, Katz HE, Mushiush M, Marks TJ. N- and P-Type Building Blocks for Organic Electronics Based on Ollgothiophene Cores. In Blom PWM, Greenham NC, Dimitrakopoulos CD, Frisbie CD, editors, Materials Research Society Symposium - Proceedings. Vol. 771. 2003. p. 397-402
Facchetti, Antonio ; Yoon, Myung Han ; Katz, Howard E. ; Mushiush, Melissa ; Marks, Tobin J. / N- and P-Type Building Blocks for Organic Electronics Based on Ollgothiophene Cores. Materials Research Society Symposium - Proceedings. editor / P.W.M. Blom ; N.C. Greenham ; C.D. Dimitrakopoulos ; C.D. Frisbie. Vol. 771 2003. pp. 397-402
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