Abstract
Electron transporting (n-channel) polymer semiconductors for field-effect transistors are rare. In this investigation, the synthesis and characterization of new electron-depleted N-alkyl-2,2′-bithiophene-3,3′- dicarboximide-based π-conjugated homopolymers and copolymers containing the 2,2′-bithiophene unit are reported. A novel design approach is employed using computational modeling to identify favorable monomer properties such as core planarity, solubilizing substituent tailorability, and appropriate electron affinity with gratifying results. Monomeric model compounds are synthesized to confirm these properties, and a crystal structure reveals a short 3.43 Å π-π stacking distance with favorable solubilizing substituent orientations. A family of 10 homopolymers and bithiophene copolymers is then synthesized via Yamamoto and Stille polymerizations, respectively. Two of these polymers are processable in common organic solvents: the homopolymer poly(N-(2-octyldodecyl)-2,2′-bithiophene-3,3′-dicarboximide) (P1) exhibits n-channel FET activity, and the copolymer poly(N-(2-octyldodecyl)-2, 2′:5′,2″:5″,2‴-quaterthiophene-3, 3′-dicarboximide) (P2) exhibits air-stable p-channel FET operation. After annealing, P1 films exhibit a very high degree of crystallinity and an electron mobility > 0.01 cm2 V-1 s-1 with a current on-off ratio of 107, which is remarkably independent of film-deposition conditions. Extraordinarily, P1 films also exhibit terracing in AFM images with a step height matching the X-ray diffraction d spacing, a rare phenomenon for polymeric organic semiconductors. Another fascinating property of these materials is the air-stable p-channel FET performance of annealed P2 films, which exhibit a hole mobility of ∼0.01 cm2 V-1 s-1 and a current on-off ratio of 107.
| Original language | English |
|---|---|
| Pages (from-to) | 9679-9694 |
| Number of pages | 16 |
| Journal | Journal of the American Chemical Society |
| Volume | 130 |
| Issue number | 30 |
| DOIs | |
| Publication status | Published - Jul 30 2008 |
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- Chemistry(all)
Cite this
n-channel polymers by design : Optimizing the interplay of solubilizing substituents, crystal packing, and field-effect transistor characteristics in polymeric bithiophene-imide semiconductors. / Letizia, Joseph A.; Salata, Michael R.; Tribout, Caitlin M.; Facchetti, Antonio; Ratner, Mark A; Marks, Tobin J.
In: Journal of the American Chemical Society, Vol. 130, No. 30, 30.07.2008, p. 9679-9694.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - n-channel polymers by design
T2 - Optimizing the interplay of solubilizing substituents, crystal packing, and field-effect transistor characteristics in polymeric bithiophene-imide semiconductors
AU - Letizia, Joseph A.
AU - Salata, Michael R.
AU - Tribout, Caitlin M.
AU - Facchetti, Antonio
AU - Ratner, Mark A
AU - Marks, Tobin J
PY - 2008/7/30
Y1 - 2008/7/30
N2 - Electron transporting (n-channel) polymer semiconductors for field-effect transistors are rare. In this investigation, the synthesis and characterization of new electron-depleted N-alkyl-2,2′-bithiophene-3,3′- dicarboximide-based π-conjugated homopolymers and copolymers containing the 2,2′-bithiophene unit are reported. A novel design approach is employed using computational modeling to identify favorable monomer properties such as core planarity, solubilizing substituent tailorability, and appropriate electron affinity with gratifying results. Monomeric model compounds are synthesized to confirm these properties, and a crystal structure reveals a short 3.43 Å π-π stacking distance with favorable solubilizing substituent orientations. A family of 10 homopolymers and bithiophene copolymers is then synthesized via Yamamoto and Stille polymerizations, respectively. Two of these polymers are processable in common organic solvents: the homopolymer poly(N-(2-octyldodecyl)-2,2′-bithiophene-3,3′-dicarboximide) (P1) exhibits n-channel FET activity, and the copolymer poly(N-(2-octyldodecyl)-2, 2′:5′,2″:5″,2‴-quaterthiophene-3, 3′-dicarboximide) (P2) exhibits air-stable p-channel FET operation. After annealing, P1 films exhibit a very high degree of crystallinity and an electron mobility > 0.01 cm2 V-1 s-1 with a current on-off ratio of 107, which is remarkably independent of film-deposition conditions. Extraordinarily, P1 films also exhibit terracing in AFM images with a step height matching the X-ray diffraction d spacing, a rare phenomenon for polymeric organic semiconductors. Another fascinating property of these materials is the air-stable p-channel FET performance of annealed P2 films, which exhibit a hole mobility of ∼0.01 cm2 V-1 s-1 and a current on-off ratio of 107.
AB - Electron transporting (n-channel) polymer semiconductors for field-effect transistors are rare. In this investigation, the synthesis and characterization of new electron-depleted N-alkyl-2,2′-bithiophene-3,3′- dicarboximide-based π-conjugated homopolymers and copolymers containing the 2,2′-bithiophene unit are reported. A novel design approach is employed using computational modeling to identify favorable monomer properties such as core planarity, solubilizing substituent tailorability, and appropriate electron affinity with gratifying results. Monomeric model compounds are synthesized to confirm these properties, and a crystal structure reveals a short 3.43 Å π-π stacking distance with favorable solubilizing substituent orientations. A family of 10 homopolymers and bithiophene copolymers is then synthesized via Yamamoto and Stille polymerizations, respectively. Two of these polymers are processable in common organic solvents: the homopolymer poly(N-(2-octyldodecyl)-2,2′-bithiophene-3,3′-dicarboximide) (P1) exhibits n-channel FET activity, and the copolymer poly(N-(2-octyldodecyl)-2, 2′:5′,2″:5″,2‴-quaterthiophene-3, 3′-dicarboximide) (P2) exhibits air-stable p-channel FET operation. After annealing, P1 films exhibit a very high degree of crystallinity and an electron mobility > 0.01 cm2 V-1 s-1 with a current on-off ratio of 107, which is remarkably independent of film-deposition conditions. Extraordinarily, P1 films also exhibit terracing in AFM images with a step height matching the X-ray diffraction d spacing, a rare phenomenon for polymeric organic semiconductors. Another fascinating property of these materials is the air-stable p-channel FET performance of annealed P2 films, which exhibit a hole mobility of ∼0.01 cm2 V-1 s-1 and a current on-off ratio of 107.
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U2 - 10.1021/ja710815a
DO - 10.1021/ja710815a
M3 - Article
VL - 130
SP - 9679
EP - 9694
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
SN - 0002-7863
IS - 30
ER -