N-, O-, and S-Tridoped Carbon-Encapsulated Co9S8 Nanomaterials: Efficient Bifunctional Electrocatalysts for Overall Water Splitting

Senchuan Huang, Yuying Meng, Shiman He, Anandarup Goswami, Qili Wu, Junhao Li, Shengfu Tong, Teddy Asefa, Mingmei Wu

Research output: Contribution to journalArticle

115 Citations (Scopus)

Abstract

The development of highly active and stable earth-abundant catalysts to reduce or eliminate the reliance on noble-metal based ones in green and sustainable (electro)chemical processes is nowadays of great interest. Here, N-, O-, and S-tridoped carbon-encapsulated Co9S8 (Co9S8 at NOSC) nanomaterials are synthesized via simple pyrolysis of S- and Co(II)-containing polypyrrole solid precursors, and the materials are proven to serve as noble metal-free bifunctional electrocatalysts for water splitting in alkaline medium. The nanomaterials exhibit remarkable catalytic performances for oxygen evolution reaction in basic electrolyte, with small overpotentials, high anodic current densities, low Tafel slopes as well as very high (nearly 100%) Faradic efficiencies. Moreover, the materials are found to efficiently electrocatalyze hydrogen evolution reaction in acidic as well as basic solutions, showing high activity in both cases and maintaining good stability in alkaline medium. A two-electrode electrolyzer assembled using the material synthesized at 900 °C (Co9S8 at NOSC-900) as an electrocatalyst at both electrodes gives current densities of 10 and 20 mA cm-2 at potentials of 1.60 and 1.74 V, respectively. The excellent electrocatalytic activity exhibited by the materials is proposed to be mainly due to the synergistic effects between the Co9S8 nanoparticles cores and the heteroatom-doped carbon shells in the materials.

Original languageEnglish
JournalAdvanced Functional Materials
DOIs
Publication statusAccepted/In press - 2017

Fingerprint

water splitting
electrocatalysts
Electrocatalysts
noble metals
Nanostructured materials
Carbon
current density
electrodes
Water
carbon
polypyrroles
pyrolysis
Precious metals
electrolytes
slopes
catalysts
Current density
nanoparticles
oxygen
hydrogen

Keywords

  • Bifunctional electrocatalysts
  • Hydrogen evolution reactions
  • Overall water splitting
  • Oxygen evolution reactions
  • Tridoped-encapsulated CoS

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Biomaterials
  • Condensed Matter Physics
  • Electrochemistry

Cite this

N-, O-, and S-Tridoped Carbon-Encapsulated Co9S8 Nanomaterials : Efficient Bifunctional Electrocatalysts for Overall Water Splitting. / Huang, Senchuan; Meng, Yuying; He, Shiman; Goswami, Anandarup; Wu, Qili; Li, Junhao; Tong, Shengfu; Asefa, Teddy; Wu, Mingmei.

In: Advanced Functional Materials, 2017.

Research output: Contribution to journalArticle

Huang, Senchuan ; Meng, Yuying ; He, Shiman ; Goswami, Anandarup ; Wu, Qili ; Li, Junhao ; Tong, Shengfu ; Asefa, Teddy ; Wu, Mingmei. / N-, O-, and S-Tridoped Carbon-Encapsulated Co9S8 Nanomaterials : Efficient Bifunctional Electrocatalysts for Overall Water Splitting. In: Advanced Functional Materials. 2017.
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