N-, O-, and S-Tridoped nanoporous carbons as selective catalysts for oxygen reduction and alcohol oxidation reactions

Yuying Meng, Damien Voiry, Anandarup Goswami, Xiaoxin Zou, Xiaoxi Huang, Manish Chhowalla, Zhongwu Liu, Teddy Asefa

Research output: Contribution to journalArticle

188 Citations (Scopus)

Abstract

Replacing rare and expensive metal catalysts with inexpensive and earth-abundant ones is currently among the major goals of sustainable chemistry. Herein we report the synthesis of N-, O-, and S-tridoped, polypyrrole-derived nanoporous carbons (NOSCs) that can serve as metal-free, selective electrocatalysts and catalysts for oxygen reduction reaction (ORR) and alcohol oxidation reaction (AOR), respectively. The NOSCs are synthesized via polymerization of pyrrole using (NH4)2S2O8 as oxidant and colloidal silica nanoparticles as templates, followed by carbonization of the resulting S-containing polypyrrole/silica composite materials and then removal of the silica templates. The NOSCs exhibit good catalytic activity toward ORR with low onset potential and low Tafel slope, along with different electron-transfer numbers, or in other words, different ratios H2O/H2O2 as products, depending on the relative amount of colloidal silica used as templates. The NOSCs also effectively catalyze AOR at relatively low temperature, giving good conversions and high selectivity.

Original languageEnglish
Pages (from-to)13554-13557
Number of pages4
JournalJournal of the American Chemical Society
Volume136
Issue number39
DOIs
Publication statusPublished - Oct 1 2014

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Silicon Dioxide
Alcohols
Carbon
Silica
Oxygen
Oxidation
Catalysts
Polypyrroles
Metals
Pyrroles
Electrocatalysts
Carbonization
Oxidants
Polymerization
Nanoparticles
Catalyst activity
Earth (planet)
Electrons
Temperature
Composite materials

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

N-, O-, and S-Tridoped nanoporous carbons as selective catalysts for oxygen reduction and alcohol oxidation reactions. / Meng, Yuying; Voiry, Damien; Goswami, Anandarup; Zou, Xiaoxin; Huang, Xiaoxi; Chhowalla, Manish; Liu, Zhongwu; Asefa, Teddy.

In: Journal of the American Chemical Society, Vol. 136, No. 39, 01.10.2014, p. 13554-13557.

Research output: Contribution to journalArticle

Meng, Yuying ; Voiry, Damien ; Goswami, Anandarup ; Zou, Xiaoxin ; Huang, Xiaoxi ; Chhowalla, Manish ; Liu, Zhongwu ; Asefa, Teddy. / N-, O-, and S-Tridoped nanoporous carbons as selective catalysts for oxygen reduction and alcohol oxidation reactions. In: Journal of the American Chemical Society. 2014 ; Vol. 136, No. 39. pp. 13554-13557.
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AU - Huang, Xiaoxi

AU - Chhowalla, Manish

AU - Liu, Zhongwu

AU - Asefa, Teddy

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