Nanoscale chemical imaging of a dynamic molecular phase boundary with ultrahigh vacuum tip-enhanced raman spectroscopy

Nan Jiang, Naihao Chiang, Lindsey R. Madison, Eric A. Pozzi, Michael R Wasielewski, Tamar Seideman, Mark A Ratner, Mark C Hersam, George C Schatz, Richard P. Van Duyne

Research output: Contribution to journalArticle

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Abstract

Nanoscale chemical imaging of a dynamic molecular phase boundary has broad implications for a range of problems in catalysis, surface science, and molecular electronics. While scanning probe microscopy (SPM) is commonly used to study molecular phase boundaries, its information content can be severely compromised by surface diffusion, irregular packing, or three-dimensional adsorbate geometry. Here, we demonstrate the simultaneous chemical and structural analysis of N-N′-bis(2,6-diisopropylphenyl)-1,7-(4′-t-butylphenoxy)perylene-3,4:9,10-bis(dicarboximide) (PPDI) molecules by UHV tip-enhanced Raman spectroscopy. Both condensed and diffusing domains of PPDI coexist on Ag(100) at room temperature. Through comparison with time-dependent density functional theory simulations, we unravel the orientation of PPDI molecules at the dynamic molecular domain boundary with unprecedented ∼4 nm spatial resolution.

Original languageEnglish
Pages (from-to)3898-3904
Number of pages7
JournalNano Letters
Volume16
Issue number6
DOIs
Publication statusPublished - Jun 8 2016

Fingerprint

Ultrahigh vacuum
Phase boundaries
ultrahigh vacuum
Raman spectroscopy
Molecular dynamics
Perylene
molecular dynamics
Imaging techniques
Molecular electronics
Scanning probe microscopy
Molecules
Surface diffusion
Adsorbates
Structural analysis
Catalysis
Density functional theory
molecular electronics
surface diffusion
chemical analysis
structural analysis

Keywords

  • dynamic molecular phase boundary
  • time-dependent density functional theory (TDDFT)
  • Tip-enhanced Raman spectroscopy (TERS)
  • ultrahigh vacuum scanning tunneling microscopy (UHV-STM)

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Bioengineering
  • Chemistry(all)
  • Materials Science(all)
  • Mechanical Engineering

Cite this

Nanoscale chemical imaging of a dynamic molecular phase boundary with ultrahigh vacuum tip-enhanced raman spectroscopy. / Jiang, Nan; Chiang, Naihao; Madison, Lindsey R.; Pozzi, Eric A.; Wasielewski, Michael R; Seideman, Tamar; Ratner, Mark A; Hersam, Mark C; Schatz, George C; Van Duyne, Richard P.

In: Nano Letters, Vol. 16, No. 6, 08.06.2016, p. 3898-3904.

Research output: Contribution to journalArticle

Jiang, Nan ; Chiang, Naihao ; Madison, Lindsey R. ; Pozzi, Eric A. ; Wasielewski, Michael R ; Seideman, Tamar ; Ratner, Mark A ; Hersam, Mark C ; Schatz, George C ; Van Duyne, Richard P. / Nanoscale chemical imaging of a dynamic molecular phase boundary with ultrahigh vacuum tip-enhanced raman spectroscopy. In: Nano Letters. 2016 ; Vol. 16, No. 6. pp. 3898-3904.
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