Nanoscale excitonic photovoltaic mechanism in ferroelectric BiFeO3 thin films

Yuelin Li, Carolina Adamo, Clare E. Rowland, Richard D Schaller, Darrell G. Schlom, Donald A. Walko

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

We report an electrode-free photovoltaic experiment in epitaxial BiFeO3 thin films where the picosecond optical absorption arising from carrier dynamics and piezoelectric lattice distortion due to the photovoltaic field are correlated at nanoscale. The data strongly suggest that the photovoltaic effect in phase-pure BiFeO3 originates from diffusion of charge-neutral excitons and their subsequent dissociation localized at sample interfaces. This is in stark contrast to the belief that carrier separation is uniform within the sample due to the lack of center of symmetry in BiFeO3. This finding is important for formulating strategies in designing practical photovoltaic ferroelectric devices.

Original languageEnglish
Article number084905
JournalAPL Materials
Volume6
Issue number8
DOIs
Publication statusPublished - Aug 1 2018

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Ferroelectric devices
Photovoltaic effects
Ferroelectric thin films
Epitaxial films
Excitons
Light absorption
Thin films
Electrodes
Experiments
LDS 751

ASJC Scopus subject areas

  • Materials Science(all)
  • Engineering(all)

Cite this

Nanoscale excitonic photovoltaic mechanism in ferroelectric BiFeO3 thin films. / Li, Yuelin; Adamo, Carolina; Rowland, Clare E.; Schaller, Richard D; Schlom, Darrell G.; Walko, Donald A.

In: APL Materials, Vol. 6, No. 8, 084905, 01.08.2018.

Research output: Contribution to journalArticle

Li, Yuelin ; Adamo, Carolina ; Rowland, Clare E. ; Schaller, Richard D ; Schlom, Darrell G. ; Walko, Donald A. / Nanoscale excitonic photovoltaic mechanism in ferroelectric BiFeO3 thin films. In: APL Materials. 2018 ; Vol. 6, No. 8.
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