Nanoscale fracture mechanics

Steven L. Mielke, Ted Belytschkobelytschko, George C. Schatz

Research output: Chapter in Book/Report/Conference proceedingChapter

34 Citations (Scopus)

Abstract

Theoretical calculations on undefected nanoscale materials predict impressive mechanical properties. In this review we summarize the status of experimental efforts to directly measure the fracture strengths of inorganic and carbon nanotubes and discuss possible explanations for the deviations between the predicted and observed values. We also summarize the role of theory in understanding the molecular-level origin of these deviations. In particular, we consider the role of defects such as vacancies, Stone-Wales defects, adatoms and ad-dimers, chemical functionalization, and oxidative pitting.

Original languageEnglish
Title of host publicationAnnual Review of Physical Chemistry
EditorsStephen Leone, Jay Groves, Rustem Ismagilov, Geraldine Richmond
Pages185-209
Number of pages25
DOIs
Publication statusPublished - Jun 12 2007

Publication series

NameAnnual Review of Physical Chemistry
Volume58
ISSN (Print)0066-426X

Keywords

  • Brittle fracture
  • Carbon nanotube fracture
  • Oxidative pitting
  • Plastic deformation
  • Stone-Wales defects
  • Vacancy defects

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

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  • Cite this

    Mielke, S. L., Belytschkobelytschko, T., & Schatz, G. C. (2007). Nanoscale fracture mechanics. In S. Leone, J. Groves, R. Ismagilov, & G. Richmond (Eds.), Annual Review of Physical Chemistry (pp. 185-209). (Annual Review of Physical Chemistry; Vol. 58). https://doi.org/10.1146/annurev.physchem.58.032806.104502