NaPdPS4 and RbPdPS4

Systems with infinite straight 1/∞ [PdPS4]- chains soluble in polar solvents and the structure of cubic RbPdPS4{Rb0.33P0.4S 2.23Ox}

Servane Coste, Jason Hanko, Martine Bujoli-Doeuff, Guy Louarn, Michel Evain, Raymond Brec, Bruno Alonso, Stéphane Jobic, Mercouri G Kanatzidis

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

The synthesis, crystal structures, chemical and spectroscopic properties of NaPdPS4, RbPdPS4, and RbPdPS4{Rb 0.33P0.4S2.23Ox} are described. NaPdPS4, RbPdPS4, are isostructural and crystallize in the tetragonal system I4/mcm with cell parameters a=7.3074(8)Å, c=12.2308(14)Å and a=8.2954(3)Å, c=12.2284(4)Å respectively. RbPdPS4{Rb0.33P0.4S2.23O x} is cubic, space group Pm-3n and a=12.0042(2)Å. All compounds contain the same 1∞[PdPS4]- chains made of alternating square planar Pd2+ cations and tetrahedral [PS 4]3- anions. RbPdPS4{Rb0.33P 0.4S2.23Ox} contains co-crystallized highly disordered molecular species encapsulated within [Rb8] cubic cavities. Spectroscopic solid state 31P NMR, infrared and Raman data as well as elemental analysis suggest that these species could be S n 2- (n=3 or 4) anions and possibly cationic [P 4S6O]6+ fragments. NaPdPS4 and RbPdPS4 exhibit exfoliative dissolution in polar solvents giving rise to solutions that show signs of complex fluid behavior.

Original languageEnglish
Pages (from-to)133-145
Number of pages13
JournalJournal of Solid State Chemistry
Volume175
Issue number2
DOIs
Publication statusPublished - Nov 2003

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Anions
Negative ions
anions
chemical properties
Cations
dissolving
Dissolution
Crystal structure
Positive ions
Nuclear magnetic resonance
fragments
Infrared radiation
solid state
cations
nuclear magnetic resonance
cavities
crystal structure
Fluids
fluids
synthesis

Keywords

  • P NMR
  • Chain-like materials
  • Complex fluid
  • Exfoliation
  • IR and Raman spectroscopies
  • Palladium
  • Thiophosphates
  • X-ray diffraction

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

NaPdPS4 and RbPdPS4 : Systems with infinite straight 1/∞ [PdPS4]- chains soluble in polar solvents and the structure of cubic RbPdPS4{Rb0.33P0.4S 2.23Ox}. / Coste, Servane; Hanko, Jason; Bujoli-Doeuff, Martine; Louarn, Guy; Evain, Michel; Brec, Raymond; Alonso, Bruno; Jobic, Stéphane; Kanatzidis, Mercouri G.

In: Journal of Solid State Chemistry, Vol. 175, No. 2, 11.2003, p. 133-145.

Research output: Contribution to journalArticle

Coste, Servane ; Hanko, Jason ; Bujoli-Doeuff, Martine ; Louarn, Guy ; Evain, Michel ; Brec, Raymond ; Alonso, Bruno ; Jobic, Stéphane ; Kanatzidis, Mercouri G. / NaPdPS4 and RbPdPS4 : Systems with infinite straight 1/∞ [PdPS4]- chains soluble in polar solvents and the structure of cubic RbPdPS4{Rb0.33P0.4S 2.23Ox}. In: Journal of Solid State Chemistry. 2003 ; Vol. 175, No. 2. pp. 133-145.
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abstract = "The synthesis, crystal structures, chemical and spectroscopic properties of NaPdPS4, RbPdPS4, and RbPdPS4{Rb 0.33P0.4S2.23Ox} are described. NaPdPS4, RbPdPS4, are isostructural and crystallize in the tetragonal system I4/mcm with cell parameters a=7.3074(8){\AA}, c=12.2308(14){\AA} and a=8.2954(3){\AA}, c=12.2284(4){\AA} respectively. RbPdPS4{Rb0.33P0.4S2.23O x} is cubic, space group Pm-3n and a=12.0042(2){\AA}. All compounds contain the same 1∞[PdPS4]- chains made of alternating square planar Pd2+ cations and tetrahedral [PS 4]3- anions. RbPdPS4{Rb0.33P 0.4S2.23Ox} contains co-crystallized highly disordered molecular species encapsulated within [Rb8] cubic cavities. Spectroscopic solid state 31P NMR, infrared and Raman data as well as elemental analysis suggest that these species could be S n 2- (n=3 or 4) anions and possibly cationic [P 4S6O]6+ fragments. NaPdPS4 and RbPdPS4 exhibit exfoliative dissolution in polar solvents giving rise to solutions that show signs of complex fluid behavior.",
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T1 - NaPdPS4 and RbPdPS4

T2 - Systems with infinite straight 1/∞ [PdPS4]- chains soluble in polar solvents and the structure of cubic RbPdPS4{Rb0.33P0.4S 2.23Ox}

AU - Coste, Servane

AU - Hanko, Jason

AU - Bujoli-Doeuff, Martine

AU - Louarn, Guy

AU - Evain, Michel

AU - Brec, Raymond

AU - Alonso, Bruno

AU - Jobic, Stéphane

AU - Kanatzidis, Mercouri G

PY - 2003/11

Y1 - 2003/11

N2 - The synthesis, crystal structures, chemical and spectroscopic properties of NaPdPS4, RbPdPS4, and RbPdPS4{Rb 0.33P0.4S2.23Ox} are described. NaPdPS4, RbPdPS4, are isostructural and crystallize in the tetragonal system I4/mcm with cell parameters a=7.3074(8)Å, c=12.2308(14)Å and a=8.2954(3)Å, c=12.2284(4)Å respectively. RbPdPS4{Rb0.33P0.4S2.23O x} is cubic, space group Pm-3n and a=12.0042(2)Å. All compounds contain the same 1∞[PdPS4]- chains made of alternating square planar Pd2+ cations and tetrahedral [PS 4]3- anions. RbPdPS4{Rb0.33P 0.4S2.23Ox} contains co-crystallized highly disordered molecular species encapsulated within [Rb8] cubic cavities. Spectroscopic solid state 31P NMR, infrared and Raman data as well as elemental analysis suggest that these species could be S n 2- (n=3 or 4) anions and possibly cationic [P 4S6O]6+ fragments. NaPdPS4 and RbPdPS4 exhibit exfoliative dissolution in polar solvents giving rise to solutions that show signs of complex fluid behavior.

AB - The synthesis, crystal structures, chemical and spectroscopic properties of NaPdPS4, RbPdPS4, and RbPdPS4{Rb 0.33P0.4S2.23Ox} are described. NaPdPS4, RbPdPS4, are isostructural and crystallize in the tetragonal system I4/mcm with cell parameters a=7.3074(8)Å, c=12.2308(14)Å and a=8.2954(3)Å, c=12.2284(4)Å respectively. RbPdPS4{Rb0.33P0.4S2.23O x} is cubic, space group Pm-3n and a=12.0042(2)Å. All compounds contain the same 1∞[PdPS4]- chains made of alternating square planar Pd2+ cations and tetrahedral [PS 4]3- anions. RbPdPS4{Rb0.33P 0.4S2.23Ox} contains co-crystallized highly disordered molecular species encapsulated within [Rb8] cubic cavities. Spectroscopic solid state 31P NMR, infrared and Raman data as well as elemental analysis suggest that these species could be S n 2- (n=3 or 4) anions and possibly cationic [P 4S6O]6+ fragments. NaPdPS4 and RbPdPS4 exhibit exfoliative dissolution in polar solvents giving rise to solutions that show signs of complex fluid behavior.

KW - P NMR

KW - Chain-like materials

KW - Complex fluid

KW - Exfoliation

KW - IR and Raman spectroscopies

KW - Palladium

KW - Thiophosphates

KW - X-ray diffraction

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U2 - 10.1016/S0022-4596(03)00138-5

DO - 10.1016/S0022-4596(03)00138-5

M3 - Article

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EP - 145

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

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