Neck formation in reactive sintering: A model 2-D experiment

Sukanya Murali, Dunbar P Birnie

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

Silica-titania sub-close-packed single layers were deposited by spin coating titanium alkoxide sols containing inert 0.5 micrometer silica particles to study the process of reactive sintering more closely than has been done before. The sub-close-packed single layers were designed to achieve a coating density such that pairs or chains of silica particles were placed on the flat substrate and held together by the reactive titania thin films overlaid on the surface and in the neck regions of these essentially 2-D particle networks. Because of the low density of silica particles, all of the two-particle junctions and neck regions were aligned for geometrically direct viewing; as a result scanning electron microscopy was useful for observing the morphology of these neck regions. Image analysis was used to quantify the neck diameter for varying titania/silica precursor concentration ratios. Geometrical calculations that relate the change in neck volume to the neck radius are presented. Implications for design of reactive sintering systems are discussed.

Original languageEnglish
Pages (from-to)1193-1197
Number of pages5
JournalJournal of Materials Research
Volume27
Issue number8
DOIs
Publication statusPublished - Apr 28 2012

Fingerprint

Silicon Dioxide
sintering
Sintering
Silica
Titanium
silicon dioxide
titanium
Experiments
Spin coating
Polymethyl Methacrylate
Sols
Image analysis
Particles (particulate matter)
alkoxides
image analysis
coating
micrometers
Thin films
Coatings
Scanning electron microscopy

Keywords

  • interparticle neck formation
  • liquid pendular bridge
  • Silica-titania
  • sintering
  • SiO -TiO
  • spin coating
  • sub-close-packed layers

ASJC Scopus subject areas

  • Materials Science(all)
  • Mechanical Engineering
  • Mechanics of Materials
  • Condensed Matter Physics

Cite this

Neck formation in reactive sintering : A model 2-D experiment. / Murali, Sukanya; Birnie, Dunbar P.

In: Journal of Materials Research, Vol. 27, No. 8, 28.04.2012, p. 1193-1197.

Research output: Contribution to journalArticle

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