New architectures for dye-sensitized solar cells

Alex B F Martinson, Thomas W. Hamann, Michael J. Pellin, Joseph T. Hupp

Research output: Contribution to journalArticle

239 Citations (Scopus)

Abstract

Modern dye-sensitized solar cell (DSSC) technology was built upon nanoparticle wide bandgap semiconductor photoanodes. While versatile and robust, the sintered nanoparticle architecture exhibits exceedingly slow electron transport that ultimately restricts the diversity of feasible redox mediators. The small collection of suitable mediators limits both our understanding of an intriguing heterogeneous system and the performance of these promising devices. Recently, a number of pseudo-1D photoanodes that exhibit accelerated charge transport and greater materials flexibility were fabricated. The potential of these alternative photoanode architectures for advancing, both directly and indirectly, the performance of DSSCs is explored.

Original languageEnglish
Pages (from-to)4458-4467
Number of pages10
JournalChemistry - A European Journal
Volume14
Issue number15
DOIs
Publication statusPublished - May 19 2008

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Nanoparticles
Charge transfer
Energy gap
Semiconductor materials
Dye-sensitized solar cells
Oxidation-Reduction
Electron Transport

Keywords

  • Atomic layer
  • Charge dynamics
  • Dyes/ pigments
  • Nanoparticles
  • Photovoltaic

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

New architectures for dye-sensitized solar cells. / Martinson, Alex B F; Hamann, Thomas W.; Pellin, Michael J.; Hupp, Joseph T.

In: Chemistry - A European Journal, Vol. 14, No. 15, 19.05.2008, p. 4458-4467.

Research output: Contribution to journalArticle

Martinson, Alex B F ; Hamann, Thomas W. ; Pellin, Michael J. ; Hupp, Joseph T. / New architectures for dye-sensitized solar cells. In: Chemistry - A European Journal. 2008 ; Vol. 14, No. 15. pp. 4458-4467.
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