New quaternary selenoantimonates AHgSbSe3 (A = Rb, Cs): synthesis, structures and optical properties

Zhen Chen; R. J. Wang; Jing Li

New quaternary selenoantimonates AHgSbSe3 (A = Rb, Cs): synthesis, structures and optical properties

Zhen Chen, R. J. Wang, Jing Li

Rutgers University

Research output: Chapter in Book/Report/Conference proceeding › Chapter

7 Citations (Scopus)

Abstract

Solvothermal reactions in ethylenediamine have resulted in two quaternary mercury containing selenoantimonates: RbHgSbSe₃ (I) and CsHgSbSe₃ (II). Compound I crystallizes in monoclinic system, space group P2₁/c (no. 14) with a = 7.758(2) angstrom, b = 11.234(2) angstrom, c = 8.849(2) angstrom, β = 106.60(3)°, V = 739.1(3) angstrom³, Z = 4. Compound II crystallizes in orthorhombic system, space group Cmcm (no. 63) with a = 4.444(1) angstrom, b = 15.514(6) angstrom, c = 11.261(7) angstrom, V = 776.4(6) angstrom³, Z = 4. Both compounds are layered materials and their crystal structures are closely related. Both contain layers of _∞ ²[HgSbSe₃ ^-] separated by alkali-metal cations A⁺ (Rb, Cs). Diffuse reflectance experiments show that both compounds are semiconductors with estimated band gaps of 1.7 eV for I and 1.6 eV for II, respectively.

Original language	English
Title of host publication	Materials Research Society Symposium - Proceedings
Publisher	Materials Research Society
Pages	419-424
Number of pages	6
Volume	547
Publication status	Published - 1999
Event	Proceedings of the 1998 MRS Fall Meeting - The Symposium 'Advanced Catalytic Materials-1998' - Boston, MA, USA Duration: Nov 30 1998 → Dec 3 1998

Other

Other	Proceedings of the 1998 MRS Fall Meeting - The Symposium 'Advanced Catalytic Materials-1998'
City	Boston, MA, USA
Period	11/30/98 → 12/3/98

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials

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title = "New quaternary selenoantimonates AHgSbSe3 (A = Rb, Cs): synthesis, structures and optical properties",

abstract = "Solvothermal reactions in ethylenediamine have resulted in two quaternary mercury containing selenoantimonates: RbHgSbSe3 (I) and CsHgSbSe3 (II). Compound I crystallizes in monoclinic system, space group P21/c (no. 14) with a = 7.758(2) angstrom, b = 11.234(2) angstrom, c = 8.849(2) angstrom, β = 106.60(3)°, V = 739.1(3) angstrom3, Z = 4. Compound II crystallizes in orthorhombic system, space group Cmcm (no. 63) with a = 4.444(1) angstrom, b = 15.514(6) angstrom, c = 11.261(7) angstrom, V = 776.4(6) angstrom3, Z = 4. Both compounds are layered materials and their crystal structures are closely related. Both contain layers of ∞ 2[HgSbSe3 -] separated by alkali-metal cations A+ (Rb, Cs). Diffuse reflectance experiments show that both compounds are semiconductors with estimated band gaps of 1.7 eV for I and 1.6 eV for II, respectively.",

author = "Zhen Chen and Wang, {R. J.} and Jing Li",

year = "1999",

language = "English",

volume = "547",

pages = "419--424",

booktitle = "Materials Research Society Symposium - Proceedings",

publisher = "Materials Research Society",

note = "Proceedings of the 1998 MRS Fall Meeting - The Symposium 'Advanced Catalytic Materials-1998' ; Conference date: 30-11-1998 Through 03-12-1998",

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TY - CHAP

T1 - New quaternary selenoantimonates AHgSbSe3 (A = Rb, Cs)

T2 - Proceedings of the 1998 MRS Fall Meeting - The Symposium 'Advanced Catalytic Materials-1998'

AU - Chen, Zhen

AU - Wang, R. J.

AU - Li, Jing

PY - 1999

Y1 - 1999

N2 - Solvothermal reactions in ethylenediamine have resulted in two quaternary mercury containing selenoantimonates: RbHgSbSe3 (I) and CsHgSbSe3 (II). Compound I crystallizes in monoclinic system, space group P21/c (no. 14) with a = 7.758(2) angstrom, b = 11.234(2) angstrom, c = 8.849(2) angstrom, β = 106.60(3)°, V = 739.1(3) angstrom3, Z = 4. Compound II crystallizes in orthorhombic system, space group Cmcm (no. 63) with a = 4.444(1) angstrom, b = 15.514(6) angstrom, c = 11.261(7) angstrom, V = 776.4(6) angstrom3, Z = 4. Both compounds are layered materials and their crystal structures are closely related. Both contain layers of ∞ 2[HgSbSe3 -] separated by alkali-metal cations A+ (Rb, Cs). Diffuse reflectance experiments show that both compounds are semiconductors with estimated band gaps of 1.7 eV for I and 1.6 eV for II, respectively.

AB - Solvothermal reactions in ethylenediamine have resulted in two quaternary mercury containing selenoantimonates: RbHgSbSe3 (I) and CsHgSbSe3 (II). Compound I crystallizes in monoclinic system, space group P21/c (no. 14) with a = 7.758(2) angstrom, b = 11.234(2) angstrom, c = 8.849(2) angstrom, β = 106.60(3)°, V = 739.1(3) angstrom3, Z = 4. Compound II crystallizes in orthorhombic system, space group Cmcm (no. 63) with a = 4.444(1) angstrom, b = 15.514(6) angstrom, c = 11.261(7) angstrom, V = 776.4(6) angstrom3, Z = 4. Both compounds are layered materials and their crystal structures are closely related. Both contain layers of ∞ 2[HgSbSe3 -] separated by alkali-metal cations A+ (Rb, Cs). Diffuse reflectance experiments show that both compounds are semiconductors with estimated band gaps of 1.7 eV for I and 1.6 eV for II, respectively.

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M3 - Chapter

AN - SCOPUS:0032591299

VL - 547

SP - 419

EP - 424

BT - Materials Research Society Symposium - Proceedings

PB - Materials Research Society

Y2 - 30 November 1998 through 3 December 1998

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