Abstract
A new low-temperature solid-state ion-exchange route has been used to ion-exchange KBi3S5. The new method allows the solid-solid ion-exchange of the K+ions for the smaller cations Li+and Na+, as well as for the NH+4at the remarkably low temperature regime of 110-130°C. The topotactically ion-exchanged seriesAxK1-xBi3S5(A=Li, Na, and NH4) was prepared and characterized by powder X-ray diffraction, differential scanning calorimetry, differential thermal analysis, thermal gravimetric analysis, semiquantitative microprobe analyses, solid-state UV/vis/near-IR spectroscopy, and variable-temperature solid-state7Li NMR spectroscopy.
| Original language | English |
|---|---|
| Pages (from-to) | 328-332 |
| Number of pages | 5 |
| Journal | Journal of Solid State Chemistry |
| Volume | 136 |
| Issue number | 2 |
| DOIs | |
| Publication status | Published - Mar 1998 |
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ASJC Scopus subject areas
- Inorganic Chemistry
- Physical and Theoretical Chemistry
- Materials Chemistry
Cite this
New Topotactic Derivatives of the Open-Framework Semiconductor KBi3S5via a Low-Temperature Solid-State Ion-Exchange Route. / Chondroudis, Konstantinos; Kanatzidis, Mercouri G.
In: Journal of Solid State Chemistry, Vol. 136, No. 2, 03.1998, p. 328-332.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - New Topotactic Derivatives of the Open-Framework Semiconductor KBi3S5via a Low-Temperature Solid-State Ion-Exchange Route
AU - Chondroudis, Konstantinos
AU - Kanatzidis, Mercouri G
PY - 1998/3
Y1 - 1998/3
N2 - A new low-temperature solid-state ion-exchange route has been used to ion-exchange KBi3S5. The new method allows the solid-solid ion-exchange of the K+ions for the smaller cations Li+and Na+, as well as for the NH+4at the remarkably low temperature regime of 110-130°C. The topotactically ion-exchanged seriesAxK1-xBi3S5(A=Li, Na, and NH4) was prepared and characterized by powder X-ray diffraction, differential scanning calorimetry, differential thermal analysis, thermal gravimetric analysis, semiquantitative microprobe analyses, solid-state UV/vis/near-IR spectroscopy, and variable-temperature solid-state7Li NMR spectroscopy.
AB - A new low-temperature solid-state ion-exchange route has been used to ion-exchange KBi3S5. The new method allows the solid-solid ion-exchange of the K+ions for the smaller cations Li+and Na+, as well as for the NH+4at the remarkably low temperature regime of 110-130°C. The topotactically ion-exchanged seriesAxK1-xBi3S5(A=Li, Na, and NH4) was prepared and characterized by powder X-ray diffraction, differential scanning calorimetry, differential thermal analysis, thermal gravimetric analysis, semiquantitative microprobe analyses, solid-state UV/vis/near-IR spectroscopy, and variable-temperature solid-state7Li NMR spectroscopy.
UR - http://www.scopus.com/inward/record.url?scp=0001661577&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0001661577&partnerID=8YFLogxK
U2 - 10.1006/jssc.1998.7812
DO - 10.1006/jssc.1998.7812
M3 - Article
VL - 136
SP - 328
EP - 332
JO - Journal of Solid State Chemistry
JF - Journal of Solid State Chemistry
SN - 0022-4596
IS - 2
ER -