New Topotactic Derivatives of the Open-Framework Semiconductor KBi                         3                         S                         5                         via a Low-Temperature Solid-State Ion-Exchange Route

Konstantinos Chondroudis; Mercouri G. Kanatzidis

doi:10.1006/jssc.1998.7812

New Topotactic Derivatives of the Open-Framework Semiconductor KBi ₃ S ₅ via a Low-Temperature Solid-State Ion-Exchange Route

Konstantinos Chondroudis, Mercouri G. Kanatzidis

Northwestern University

Research output: Contribution to journal › Editorial › peer-review

18 Citations (Scopus)

Abstract

A new low-temperature solid-state ion-exchange route has been used to ion-exchange KBi ₃ S ₅ . The new method allows the solid-solid ion-exchange of the K ⁺ ions for the smaller cations Li ⁺ and Na ⁺ , as well as for the NH ⁺ ₄ at the remarkably low temperature regime of 110-130°C. The topotactically ion-exchanged seriesA _x K _1-x Bi ₃ S ₅ (A=Li, Na, and NH ₄ ) was prepared and characterized by powder X-ray diffraction, differential scanning calorimetry, differential thermal analysis, thermal gravimetric analysis, semiquantitative microprobe analyses, solid-state UV/vis/near-IR spectroscopy, and variable-temperature solid-state ⁷ Li NMR spectroscopy.

Original language	English
Pages (from-to)	328-332
Number of pages	5
Journal	Journal of Solid State Chemistry
Volume	136
Issue number	2
DOIs	https://doi.org/10.1006/jssc.1998.7812
Publication status	Published - Mar 1998

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Ceramics and Composites
Condensed Matter Physics
Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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Chondroudis, K., & Kanatzidis, M. G. (1998). New Topotactic Derivatives of the Open-Framework Semiconductor KBi ₃ S ₅ via a Low-Temperature Solid-State Ion-Exchange Route Journal of Solid State Chemistry, 136(2), 328-332. https://doi.org/10.1006/jssc.1998.7812

New Topotactic Derivatives of the Open-Framework Semiconductor KBi ₃ S ₅ via a Low-Temperature Solid-State Ion-Exchange Route . / Chondroudis, Konstantinos; Kanatzidis, Mercouri G.

In: Journal of Solid State Chemistry, Vol. 136, No. 2, 03.1998, p. 328-332.

Research output: Contribution to journal › Editorial › peer-review

Chondroudis, K & Kanatzidis, MG 1998, ' New Topotactic Derivatives of the Open-Framework Semiconductor KBi ₃ S ₅ via a Low-Temperature Solid-State Ion-Exchange Route ', Journal of Solid State Chemistry, vol. 136, no. 2, pp. 328-332. https://doi.org/10.1006/jssc.1998.7812

Chondroudis K, Kanatzidis MG. New Topotactic Derivatives of the Open-Framework Semiconductor KBi ₃ S ₅ via a Low-Temperature Solid-State Ion-Exchange Route Journal of Solid State Chemistry. 1998 Mar;136(2):328-332. https://doi.org/10.1006/jssc.1998.7812

Chondroudis, Konstantinos ; Kanatzidis, Mercouri G. / New Topotactic Derivatives of the Open-Framework Semiconductor KBi ₃ S ₅ via a Low-Temperature Solid-State Ion-Exchange Route In: Journal of Solid State Chemistry. 1998 ; Vol. 136, No. 2. pp. 328-332.

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title = " New Topotactic Derivatives of the Open-Framework Semiconductor KBi 3 S 5 via a Low-Temperature Solid-State Ion-Exchange Route ",

abstract = " A new low-temperature solid-state ion-exchange route has been used to ion-exchange KBi 3 S 5 . The new method allows the solid-solid ion-exchange of the K + ions for the smaller cations Li + and Na + , as well as for the NH + 4 at the remarkably low temperature regime of 110-130°C. The topotactically ion-exchanged seriesA x K 1-x Bi 3 S 5 (A=Li, Na, and NH 4 ) was prepared and characterized by powder X-ray diffraction, differential scanning calorimetry, differential thermal analysis, thermal gravimetric analysis, semiquantitative microprobe analyses, solid-state UV/vis/near-IR spectroscopy, and variable-temperature solid-state 7 Li NMR spectroscopy.",

author = "Konstantinos Chondroudis and Kanatzidis, {Mercouri G.}",

note = "Funding Information: Financial support from the National Science Foundation Grant CHE 96-33798 (Chemistry Research Group) is gratefully acknowledged. Copyright: Copyright 2019 Elsevier B.V., All rights reserved.",

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AU - Chondroudis, Konstantinos

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N1 - Funding Information: Financial support from the National Science Foundation Grant CHE 96-33798 (Chemistry Research Group) is gratefully acknowledged. Copyright: Copyright 2019 Elsevier B.V., All rights reserved.

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AB - A new low-temperature solid-state ion-exchange route has been used to ion-exchange KBi 3 S 5 . The new method allows the solid-solid ion-exchange of the K + ions for the smaller cations Li + and Na + , as well as for the NH + 4 at the remarkably low temperature regime of 110-130°C. The topotactically ion-exchanged seriesA x K 1-x Bi 3 S 5 (A=Li, Na, and NH 4 ) was prepared and characterized by powder X-ray diffraction, differential scanning calorimetry, differential thermal analysis, thermal gravimetric analysis, semiquantitative microprobe analyses, solid-state UV/vis/near-IR spectroscopy, and variable-temperature solid-state 7 Li NMR spectroscopy.

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New Topotactic Derivatives of the Open-Framework Semiconductor KBi 3 S 5 via a Low-Temperature Solid-State Ion-Exchange Route

Abstract

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New Topotactic Derivatives of the Open-Framework Semiconductor KBi ₃ S ₅ via a Low-Temperature Solid-State Ion-Exchange Route