Ni-Mo nanopowders for efficient electrochemical hydrogen evolution

James R. McKone, Bryce F. Sadtler, Caroline A. Werlang, Nathan S Lewis, Harry B. Gray

Research output: Contribution to journalArticle

401 Citations (Scopus)

Abstract

Earth-abundant metals are attractive alternatives to the noble metal composite catalysts that are used in water electrolyzers based on proton-exchange membrane technology. Ni-Mo alloys have been previously developed for the hydrogen evolution reaction (HER), but synthesis methods to date have been limited to formation of catalyst coatings directly on a substrate. We report a method for generating unsupported nanopowders of Ni-Mo, which can be suspended in common solvents and cast onto arbitrary substrates. The mass-specific catalytic activity under alkaline conditions approaches that of the most active reported non-noble HER catalysts, and the coatings display good stability under alkaline conditions. We have also estimated turnover frequencies per surface atom at various overpotentials and conclude that the activity enhancement for Ni-Mo relative to pure Ni is due to a combination of increased surface area and increased fundamental catalytic activity.

Original languageEnglish
Pages (from-to)166-169
Number of pages4
JournalACS Catalysis
Volume3
Issue number2
DOIs
Publication statusPublished - Feb 1 2013

Fingerprint

Hydrogen
Catalysts
Catalyst activity
Membrane technology
Coatings
Substrates
Precious metals
Protons
Ion exchange
Metals
Earth (planet)
Atoms
Water
Composite materials

Keywords

  • cathode
  • electrolysis
  • HER
  • hydrogen evolution
  • molybdenum
  • Ni-Mo
  • nickel
  • stability

ASJC Scopus subject areas

  • Catalysis

Cite this

McKone, J. R., Sadtler, B. F., Werlang, C. A., Lewis, N. S., & Gray, H. B. (2013). Ni-Mo nanopowders for efficient electrochemical hydrogen evolution. ACS Catalysis, 3(2), 166-169. https://doi.org/10.1021/cs300691m

Ni-Mo nanopowders for efficient electrochemical hydrogen evolution. / McKone, James R.; Sadtler, Bryce F.; Werlang, Caroline A.; Lewis, Nathan S; Gray, Harry B.

In: ACS Catalysis, Vol. 3, No. 2, 01.02.2013, p. 166-169.

Research output: Contribution to journalArticle

McKone, JR, Sadtler, BF, Werlang, CA, Lewis, NS & Gray, HB 2013, 'Ni-Mo nanopowders for efficient electrochemical hydrogen evolution', ACS Catalysis, vol. 3, no. 2, pp. 166-169. https://doi.org/10.1021/cs300691m
McKone, James R. ; Sadtler, Bryce F. ; Werlang, Caroline A. ; Lewis, Nathan S ; Gray, Harry B. / Ni-Mo nanopowders for efficient electrochemical hydrogen evolution. In: ACS Catalysis. 2013 ; Vol. 3, No. 2. pp. 166-169.
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