Nickel-Carbon-Zirconium Material Derived from Nickel-Oxide Clusters Installed in a Metal-Organic Framework Scaffold by Atomic Layer Deposition

Rebecca H. Palmer, Chung Wei Kung, Jian Liu, Omar K. Farha, Joseph T Hupp

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

Atomic layer deposition is employed to install nickel oxide into NU-1000. Upon heating to 900 °C under nitrogen, a carbon material containing ZrO2 and Ni is formed. In notable contrast to the parent metal-organic framework, the pyrolyzed material is: (a) stable in highly alkaline solutions (typical conditions for water electro-oxidation) and (b) electrically conductive and thus able to deliver oxidizing equivalents (holes) to catalytic sites located far from the underlying conductive-glass electrode. The pyrolysis-derived material was characterized and its electrocatalytic activity for oxygen evolution was investigated.

Original languageEnglish
Pages (from-to)14143-14150
Number of pages8
JournalLangmuir
Volume34
Issue number47
DOIs
Publication statusPublished - Nov 27 2018

Fingerprint

glass electrodes
Nickel oxide
Atomic layer deposition
nickel oxides
atomic layer epitaxy
Nickel
Zirconium
Scaffolds
pyrolysis
Carbon
Metals
nickel
nitrogen
oxidation
heating
carbon
oxygen
metals
water
Electrooxidation

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Spectroscopy
  • Electrochemistry

Cite this

Nickel-Carbon-Zirconium Material Derived from Nickel-Oxide Clusters Installed in a Metal-Organic Framework Scaffold by Atomic Layer Deposition. / Palmer, Rebecca H.; Kung, Chung Wei; Liu, Jian; Farha, Omar K.; Hupp, Joseph T.

In: Langmuir, Vol. 34, No. 47, 27.11.2018, p. 14143-14150.

Research output: Contribution to journalArticle

Palmer, Rebecca H. ; Kung, Chung Wei ; Liu, Jian ; Farha, Omar K. ; Hupp, Joseph T. / Nickel-Carbon-Zirconium Material Derived from Nickel-Oxide Clusters Installed in a Metal-Organic Framework Scaffold by Atomic Layer Deposition. In: Langmuir. 2018 ; Vol. 34, No. 47. pp. 14143-14150.
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