Abstract
Atomic layer deposition is employed to install nickel oxide into NU-1000. Upon heating to 900 °C under nitrogen, a carbon material containing ZrO2 and Ni is formed. In notable contrast to the parent metal-organic framework, the pyrolyzed material is: (a) stable in highly alkaline solutions (typical conditions for water electro-oxidation) and (b) electrically conductive and thus able to deliver oxidizing equivalents (holes) to catalytic sites located far from the underlying conductive-glass electrode. The pyrolysis-derived material was characterized and its electrocatalytic activity for oxygen evolution was investigated.
| Original language | English |
|---|---|
| Pages (from-to) | 14143-14150 |
| Number of pages | 8 |
| Journal | Langmuir |
| Volume | 34 |
| Issue number | 47 |
| DOIs | |
| Publication status | Published - Nov 27 2018 |
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ASJC Scopus subject areas
- Materials Science(all)
- Condensed Matter Physics
- Surfaces and Interfaces
- Spectroscopy
- Electrochemistry
Cite this
Nickel-Carbon-Zirconium Material Derived from Nickel-Oxide Clusters Installed in a Metal-Organic Framework Scaffold by Atomic Layer Deposition. / Palmer, Rebecca H.; Kung, Chung Wei; Liu, Jian; Farha, Omar K.; Hupp, Joseph T.
In: Langmuir, Vol. 34, No. 47, 27.11.2018, p. 14143-14150.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Nickel-Carbon-Zirconium Material Derived from Nickel-Oxide Clusters Installed in a Metal-Organic Framework Scaffold by Atomic Layer Deposition
AU - Palmer, Rebecca H.
AU - Kung, Chung Wei
AU - Liu, Jian
AU - Farha, Omar K.
AU - Hupp, Joseph T
PY - 2018/11/27
Y1 - 2018/11/27
N2 - Atomic layer deposition is employed to install nickel oxide into NU-1000. Upon heating to 900 °C under nitrogen, a carbon material containing ZrO2 and Ni is formed. In notable contrast to the parent metal-organic framework, the pyrolyzed material is: (a) stable in highly alkaline solutions (typical conditions for water electro-oxidation) and (b) electrically conductive and thus able to deliver oxidizing equivalents (holes) to catalytic sites located far from the underlying conductive-glass electrode. The pyrolysis-derived material was characterized and its electrocatalytic activity for oxygen evolution was investigated.
AB - Atomic layer deposition is employed to install nickel oxide into NU-1000. Upon heating to 900 °C under nitrogen, a carbon material containing ZrO2 and Ni is formed. In notable contrast to the parent metal-organic framework, the pyrolyzed material is: (a) stable in highly alkaline solutions (typical conditions for water electro-oxidation) and (b) electrically conductive and thus able to deliver oxidizing equivalents (holes) to catalytic sites located far from the underlying conductive-glass electrode. The pyrolysis-derived material was characterized and its electrocatalytic activity for oxygen evolution was investigated.
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UR - http://www.scopus.com/inward/citedby.url?scp=85057193697&partnerID=8YFLogxK
U2 - 10.1021/acs.langmuir.8b02166
DO - 10.1021/acs.langmuir.8b02166
M3 - Article
VL - 34
SP - 14143
EP - 14150
JO - Langmuir
JF - Langmuir
SN - 0743-7463
IS - 47
ER -