Nickel complexes of a binucleating ligand derived from an SCS pincer

Sonja M. Peterson, Monte L. Helm, Aaron M. Appel

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10 Citations (Scopus)

Abstract

A binucleating ligand has been prepared that contains an SCS pincer and three oxygen donor atoms in a partial crown ether loop. To enable metalation with Ni0, a bromoarene precursor was used and resulted in the formation of a nickel-bromide complex in the SCS pincer portion of the ligand. Reaction of the nickel complex with a lithium salt yielded a heterobimetallic complex with bromide bridging the two metal centers. The solid-state structures were determined for this heterobimetallic complex and the nickel-bromide precursor, and the two complexes were characterized electrochemically to determine the influence of coordinating the second metal. This journal is

Original languageEnglish
Pages (from-to)747-752
Number of pages6
JournalDalton Transactions
Volume44
Issue number2
DOIs
Publication statusPublished - Jan 14 2015

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ASJC Scopus subject areas

  • Inorganic Chemistry

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