Nickel complexes of a binucleating ligand derived from an SCS pincer

Sonja M. Peterson; Monte Helm; Aaron Appel

doi:10.1039/c4dt02718c

Nickel complexes of a binucleating ligand derived from an SCS pincer

Sonja M. Peterson, Monte Helm, Aaron Appel

Pacific Northwest National Laboratory

Research output: Contribution to journal › Article

10 Citations (Scopus)

Abstract

A binucleating ligand has been prepared that contains an SCS pincer and three oxygen donor atoms in a partial crown ether loop. To enable metalation with Ni⁰, a bromoarene precursor was used and resulted in the formation of a nickel-bromide complex in the SCS pincer portion of the ligand. Reaction of the nickel complex with a lithium salt yielded a heterobimetallic complex with bromide bridging the two metal centers. The solid-state structures were determined for this heterobimetallic complex and the nickel-bromide precursor, and the two complexes were characterized electrochemically to determine the influence of coordinating the second metal. This journal is

Original language	English
Pages (from-to)	747-752
Number of pages	6
Journal	Dalton Transactions
Volume	44
Issue number	2
DOIs	https://doi.org/10.1039/c4dt02718c
Publication status	Published - Jan 14 2015

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Nickel

Bromides

Ligands

Metals

Crown Ethers

Lithium

Salts

Oxygen

Atoms

ASJC Scopus subject areas

Inorganic Chemistry

Cite this

Peterson, S. M., Helm, M., & Appel, A. (2015). Nickel complexes of a binucleating ligand derived from an SCS pincer. Dalton Transactions, 44(2), 747-752. https://doi.org/10.1039/c4dt02718c

Nickel complexes of a binucleating ligand derived from an SCS pincer. / Peterson, Sonja M.; Helm, Monte ; Appel, Aaron.

In: Dalton Transactions, Vol. 44, No. 2, 14.01.2015, p. 747-752.

Research output: Contribution to journal › Article

Peterson, SM, Helm, M & Appel, A 2015, 'Nickel complexes of a binucleating ligand derived from an SCS pincer', Dalton Transactions, vol. 44, no. 2, pp. 747-752. https://doi.org/10.1039/c4dt02718c

Peterson SM, Helm M , Appel A. Nickel complexes of a binucleating ligand derived from an SCS pincer. Dalton Transactions. 2015 Jan 14;44(2):747-752. https://doi.org/10.1039/c4dt02718c

Peterson, Sonja M. ; Helm, Monte ; Appel, Aaron. / Nickel complexes of a binucleating ligand derived from an SCS pincer. In: Dalton Transactions. 2015 ; Vol. 44, No. 2. pp. 747-752.

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10.1039/c4dt02718c