Abstract
A binucleating ligand has been prepared that contains an SCS pincer and three oxygen donor atoms in a partial crown ether loop. To enable metalation with Ni0, a bromoarene precursor was used and resulted in the formation of a nickel-bromide complex in the SCS pincer portion of the ligand. Reaction of the nickel complex with a lithium salt yielded a heterobimetallic complex with bromide bridging the two metal centers. The solid-state structures were determined for this heterobimetallic complex and the nickel-bromide precursor, and the two complexes were characterized electrochemically to determine the influence of coordinating the second metal. This journal is
Original language | English |
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Pages (from-to) | 747-752 |
Number of pages | 6 |
Journal | Dalton Transactions |
Volume | 44 |
Issue number | 2 |
DOIs | |
Publication status | Published - Jan 14 2015 |
ASJC Scopus subject areas
- Inorganic Chemistry