Abstract
Nickel phosphine complexes with pendant amines have been found to be electrocatalysts for the oxidation of primary and secondary alcohols, with turnover frequencies as high as 3.3 s-1. These complexes are the first electrocatalysts for alcohol oxidation based on non-precious metals, which will be critical for use in fuel cells.
| Original language | English |
|---|---|
| Pages (from-to) | 6172-6174 |
| Number of pages | 3 |
| Journal | Chemical Communications |
| Volume | 51 |
| Issue number | 28 |
| DOIs | |
| Publication status | Published - Apr 11 2015 |
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ASJC Scopus subject areas
- Chemistry(all)
- Catalysis
- Ceramics and Composites
- Electronic, Optical and Magnetic Materials
- Surfaces, Coatings and Films
- Materials Chemistry
- Metals and Alloys
Cite this
Nickel phosphine catalysts with pendant amines for electrocatalytic oxidation of alcohols. / Weiss, Charles J.; Wiedner, Eric; Roberts, John; Appel, Aaron.
In: Chemical Communications, Vol. 51, No. 28, 11.04.2015, p. 6172-6174.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Nickel phosphine catalysts with pendant amines for electrocatalytic oxidation of alcohols
AU - Weiss, Charles J.
AU - Wiedner, Eric
AU - Roberts, John
AU - Appel, Aaron
PY - 2015/4/11
Y1 - 2015/4/11
N2 - Nickel phosphine complexes with pendant amines have been found to be electrocatalysts for the oxidation of primary and secondary alcohols, with turnover frequencies as high as 3.3 s-1. These complexes are the first electrocatalysts for alcohol oxidation based on non-precious metals, which will be critical for use in fuel cells.
AB - Nickel phosphine complexes with pendant amines have been found to be electrocatalysts for the oxidation of primary and secondary alcohols, with turnover frequencies as high as 3.3 s-1. These complexes are the first electrocatalysts for alcohol oxidation based on non-precious metals, which will be critical for use in fuel cells.
UR - http://www.scopus.com/inward/record.url?scp=84925815644&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84925815644&partnerID=8YFLogxK
U2 - 10.1039/c5cc01107h
DO - 10.1039/c5cc01107h
M3 - Article
AN - SCOPUS:84925815644
VL - 51
SP - 6172
EP - 6174
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 28
ER -