Nickel phosphine catalysts with pendant amines for electrocatalytic oxidation of alcohols

Charles J. Weiss; Eric S. Wiedner; John A.S. Roberts; Aaron M. Appel

doi:10.1039/c5cc01107h

Nickel phosphine catalysts with pendant amines for electrocatalytic oxidation of alcohols

Charles J. Weiss, Eric S. Wiedner, John A.S. Roberts, Aaron M. Appel

Pacific Northwest National Laboratory

Research output: Contribution to journal › Article › peer-review

26 Citations (Scopus)

Abstract

Nickel phosphine complexes with pendant amines have been found to be electrocatalysts for the oxidation of primary and secondary alcohols, with turnover frequencies as high as 3.3 s^-1. These complexes are the first electrocatalysts for alcohol oxidation based on non-precious metals, which will be critical for use in fuel cells.

Original language	English
Pages (from-to)	6172-6174
Number of pages	3
Journal	Chemical Communications
Volume	51
Issue number	28
DOIs	https://doi.org/10.1039/c5cc01107h
Publication status	Published - Apr 11 2015

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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abstract = "Nickel phosphine complexes with pendant amines have been found to be electrocatalysts for the oxidation of primary and secondary alcohols, with turnover frequencies as high as 3.3 s-1. These complexes are the first electrocatalysts for alcohol oxidation based on non-precious metals, which will be critical for use in fuel cells.",

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