Non-covalent immobilization of homogeneous cationic chiral rhodium-phosphine catalysts on silica surfaces

F. M. De Rege, D. K. Morita, K. C. Ott, William Tumas, R. D. Broene

Research output: Contribution to journalArticle

86 Citations (Scopus)

Abstract

Non-covalent immobilization of [(R,R)-Me-(DuPHOS)Rh-(COD)]OTf by interaction of the triflate counter ion with surface silanols of silica supports leads to an active, stable, enantioselective, asymmetric hydrogenation catalyst.

Original languageEnglish
Pages (from-to)1797-1798
Number of pages2
JournalChemical Communications
Issue number18
Publication statusPublished - Sep 21 2000

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phosphine
Rhodium
Radiation counters
Silicon Dioxide
Hydrogenation
Silica
Catalysts
silanol

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Non-covalent immobilization of homogeneous cationic chiral rhodium-phosphine catalysts on silica surfaces. / De Rege, F. M.; Morita, D. K.; Ott, K. C.; Tumas, William; Broene, R. D.

In: Chemical Communications, No. 18, 21.09.2000, p. 1797-1798.

Research output: Contribution to journalArticle

De Rege, F. M. ; Morita, D. K. ; Ott, K. C. ; Tumas, William ; Broene, R. D. / Non-covalent immobilization of homogeneous cationic chiral rhodium-phosphine catalysts on silica surfaces. In: Chemical Communications. 2000 ; No. 18. pp. 1797-1798.
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