Non-covalent immobilization of homogeneous cationic chiral rhodium-phosphine catalysts on silica surfaces

F. M. De Rege, D. K. Morita, K. C. Ott, W. Tumas, R. D. Broene

Research output: Contribution to journalArticle

85 Citations (Scopus)

Abstract

Non-covalent immobilization of [(R,R)-Me-(DuPHOS)Rh-(COD)]OTf by interaction of the triflate counter ion with surface silanols of silica supports leads to an active, stable, enantioselective, asymmetric hydrogenation catalyst.

Original languageEnglish
Pages (from-to)1797-1798
Number of pages2
JournalChemical Communications
Issue number18
DOIs
Publication statusPublished - Sep 21 2000

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ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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