Nonlinear optical response of molecule in inhomogeneous solvation environment: A response theory formalism

Solvejg Jørgensen; Mark A. Ratner; Kurt V. Mikkelsen

doi:10.1063/1.1400127

Nonlinear optical response of molecule in inhomogeneous solvation environment: A response theory formalism

Solvejg Jørgensen, Mark A. Ratner, Kurt V. Mikkelsen

Northwestern University

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15 Citations (Scopus)

Abstract

A method that enables the determination of quadratic response molecular properties of heterogeneously solvated molecules is presented. The method describes the situation where a solvated molecule is located on a metallic surface. It is demonstrated that the two-photon matrix elements and the frequency-dependent hyperpolarizabilities for a heterogeneously solvated CO molecule depend on the distance to the metal surface and the dielectric constant of the solvent.

Original language	English
Pages (from-to)	8185-8192
Number of pages	8
Journal	Journal of Chemical Physics
Volume	115
Issue number	17
DOIs	https://doi.org/10.1063/1.1400127
Publication status	Published - Nov 1 2001

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ASJC Scopus subject areas

Physics and Astronomy(all)
Physical and Theoretical Chemistry

Cite this

Jørgensen, S., Ratner, M. A., & Mikkelsen, K. V. (2001). Nonlinear optical response of molecule in inhomogeneous solvation environment: A response theory formalism. Journal of Chemical Physics, 115(17), 8185-8192. https://doi.org/10.1063/1.1400127

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Access to Document

10.1063/1.1400127