Novel azine reactivity: Facile N-N bond cleavage, C-H activation, and N-N coupling mediated by RhI

Revital Cohen; Boris Rybtchinski; Mark Gandelman; Linda J.W. Shimon; Jan M.L. Martin; David Milstein

doi:10.1002/anie.200250571

Novel azine reactivity: Facile N-N bond cleavage, C-H activation, and N-N coupling mediated by Rh^I

Revital Cohen, Boris Rybtchinski, Mark Gandelman, Linda J.W. Shimon, Jan M.L. Martin, David Milstein

Weizmann Institute of Science, Israel

Research output: Contribution to journal › Article › peer-review

36 Citations (Scopus)

Abstract

An unprecedented reaction: Dinitrogen pincer Rh complexes react with azines in a moderately catalytic fashion by "nonsymmetrical" N-N bond cleavage to the corresponding nitriles and imines (see scheme).

Original language	English
Pages (from-to)	1949-1952
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	42
Issue number	17
DOIs	https://doi.org/10.1002/anie.200250571
Publication status	Published - Apr 29 2003

Keywords

Azines
C-H activation
Density functional calculations
N-N activation
Pincer ligands

ASJC Scopus subject areas

Catalysis
Chemistry(all)

Access to Document

10.1002/anie.200250571

Fingerprint Dive into the research topics of 'Novel azine reactivity: Facile N-N bond cleavage, C-H activation, and N-N coupling mediated by Rh<sup>I</sup>'. Together they form a unique fingerprint.

Cite this

@article{ba46508ec1914ba7b74ad02995769fc7,

title = "Novel azine reactivity: Facile N-N bond cleavage, C-H activation, and N-N coupling mediated by RhI",

abstract = "An unprecedented reaction: Dinitrogen pincer Rh complexes react with azines in a moderately catalytic fashion by {"}nonsymmetrical{"} N-N bond cleavage to the corresponding nitriles and imines (see scheme).",

keywords = "Azines, C-H activation, Density functional calculations, N-N activation, Pincer ligands",

author = "Revital Cohen and Boris Rybtchinski and Mark Gandelman and Shimon, {Linda J.W.} and Martin, {Jan M.L.} and David Milstein",

year = "2003",

month = apr,

day = "29",

doi = "10.1002/anie.200250571",

language = "English",

volume = "42",

pages = "1949--1952",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "17",

}

TY - JOUR

T1 - Novel azine reactivity

T2 - Facile N-N bond cleavage, C-H activation, and N-N coupling mediated by RhI

AU - Cohen, Revital

AU - Rybtchinski, Boris

AU - Gandelman, Mark

AU - Shimon, Linda J.W.

AU - Martin, Jan M.L.

AU - Milstein, David

PY - 2003/4/29

Y1 - 2003/4/29

N2 - An unprecedented reaction: Dinitrogen pincer Rh complexes react with azines in a moderately catalytic fashion by "nonsymmetrical" N-N bond cleavage to the corresponding nitriles and imines (see scheme).

AB - An unprecedented reaction: Dinitrogen pincer Rh complexes react with azines in a moderately catalytic fashion by "nonsymmetrical" N-N bond cleavage to the corresponding nitriles and imines (see scheme).

KW - Azines

KW - C-H activation

KW - Density functional calculations

KW - N-N activation

KW - Pincer ligands

UR - http://www.scopus.com/inward/record.url?scp=0037878059&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0037878059&partnerID=8YFLogxK

U2 - 10.1002/anie.200250571

DO - 10.1002/anie.200250571

M3 - Article

C2 - 12730978

AN - SCOPUS:0037878059

VL - 42

SP - 1949

EP - 1952

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

SN - 1433-7851

IS - 17

ER -