Novel azine reactivity: Facile N-N bond cleavage, C-H activation, and N-N coupling mediated by RhI

Revital Cohen; Boris Rybtchinski; Mark Gandelman; Linda J.W. Shimon; Jan M.L. Martin; David Milstein

doi:10.1002/anie.200250571

Novel azine reactivity: Facile N-N bond cleavage, C-H activation, and N-N coupling mediated by Rh^I

Revital Cohen, Boris Rybtchinski, Mark Gandelman, Linda J.W. Shimon, Jan M.L. Martin, David Milstein

Weizmann Institute of Science, Israel

Research output: Contribution to journal › Article

36 Citations (Scopus)

Abstract

An unprecedented reaction: Dinitrogen pincer Rh complexes react with azines in a moderately catalytic fashion by "nonsymmetrical" N-N bond cleavage to the corresponding nitriles and imines (see scheme).

Original language	English
Pages (from-to)	1949-1952
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	42
Issue number	17
DOIs	https://doi.org/10.1002/anie.200250571
Publication status	Published - Apr 29 2003

Keywords

Azines
C-H activation
Density functional calculations
N-N activation
Pincer ligands

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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Cohen, R., Rybtchinski, B., Gandelman, M., Shimon, L. J. W., Martin, J. M. L., & Milstein, D. (2003). Novel azine reactivity: Facile N-N bond cleavage, C-H activation, and N-N coupling mediated by Rh^I. Angewandte Chemie - International Edition, 42(17), 1949-1952. https://doi.org/10.1002/anie.200250571

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