Novel azine reactivity

Facile N-N bond cleavage, C-H activation, and N-N coupling mediated by RhI

Revital Cohen, Boris Rybtchinski, Mark Gandelman, Linda J W Shimon, Jan M L Martin, David Milstein

Research output: Contribution to journal › Article

36 Citations (Scopus)

Abstract

An unprecedented reaction: Dinitrogen pincer Rh complexes react with azines in a moderately catalytic fashion by "nonsymmetrical" N-N bond cleavage to the corresponding nitriles and imines (see scheme).

Original languageEnglish
Pages (from-to)1949-1952
Number of pages4
JournalAngewandte Chemie - International Edition
Volume42
Issue number17
DOIs
Publication statusPublished - Apr 29 2003

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Nitriles
Imines
Chemical activation

Keywords

  • Azines
  • C-H activation
  • Density functional calculations
  • N-N activation
  • Pincer ligands

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Novel azine reactivity : Facile N-N bond cleavage, C-H activation, and N-N coupling mediated by RhI. / Cohen, Revital; Rybtchinski, Boris; Gandelman, Mark; Shimon, Linda J W; Martin, Jan M L; Milstein, David.

In: Angewandte Chemie - International Edition, Vol. 42, No. 17, 29.04.2003, p. 1949-1952.

Research output: Contribution to journal › Article

Cohen, R, Rybtchinski, B, Gandelman, M, Shimon, LJW, Martin, JML & Milstein, D 2003, 'Novel azine reactivity: Facile N-N bond cleavage, C-H activation, and N-N coupling mediated by RhI', Angewandte Chemie - International Edition, vol. 42, no. 17, pp. 1949-1952. https://doi.org/10.1002/anie.200250571
Cohen R, Rybtchinski B, Gandelman M, Shimon LJW, Martin JML, Milstein D. Novel azine reactivity: Facile N-N bond cleavage, C-H activation, and N-N coupling mediated by RhI. Angewandte Chemie - International Edition. 2003 Apr 29;42(17):1949-1952. https://doi.org/10.1002/anie.200250571
Cohen, Revital ; Rybtchinski, Boris ; Gandelman, Mark ; Shimon, Linda J W ; Martin, Jan M L ; Milstein, David. / Novel azine reactivity : Facile N-N bond cleavage, C-H activation, and N-N coupling mediated by RhI. In: Angewandte Chemie - International Edition. 2003 ; Vol. 42, No. 17. pp. 1949-1952.
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