Novel single- and double-layer and three-dimensional structures of rare- Earth metal coordination polymers: The effect of lanthanide contraction and acidity control in crystal structure formation

Long Pan; Xiaoying Huang; Jing Li; Yonggang Wu; Nengwu Zheng

doi:10.1002/(SICI)1521-3773(20000204)39:3<527::AID-ANIE527>3.0.CO;2-W

Novel single- and double-layer and three-dimensional structures of rare- Earth metal coordination polymers: The effect of lanthanide contraction and acidity control in crystal structure formation

Long Pan, Xiaoying Huang, Jing Li, Yonggang Wu, Nengwu Zheng

Rutgers University

Research output: Contribution to journal › Article

439 Citations (Scopus)

Abstract

Lanthanide atom sizes (the lanthanide contraction) directly control the type of structure formed by the coordination of a single multidentate ligand, 3,5-pyrazoledicarboxylic acid (H₃pdc). Single-layer, double-layer ([Eu₂(Hpdc)₃(H₂O)₆], see picture), and three-dimensional networks were found. Control of the reaction pH plays a key role in the structure formation in this system.

Original language	English
Pages (from-to)	527-530
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	39
Issue number	3
DOIs	https://doi.org/10.1002/(SICI)1521-3773(20000204)39:3<527::AID-ANIE527>3.0.CO;2-W
Publication status	Published - Feb 4 2000

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Keywords

Coordination modes
Hydrothermal synthesis
Lanthanides
Rare-earth compounds

ASJC Scopus subject areas

Chemistry(all)

Cite this

Pan, L., Huang, X., Li, J., Wu, Y., & Zheng, N. (2000). Novel single- and double-layer and three-dimensional structures of rare- Earth metal coordination polymers: The effect of lanthanide contraction and acidity control in crystal structure formation. Angewandte Chemie - International Edition, 39(3), 527-530. https://doi.org/10.1002/(SICI)1521-3773(20000204)39:3<527::AID-ANIE527>3.0.CO;2-W

Novel single- and double-layer and three-dimensional structures of rare- Earth metal coordination polymers : The effect of lanthanide contraction and acidity control in crystal structure formation. / Pan, Long; Huang, Xiaoying; Li, Jing; Wu, Yonggang; Zheng, Nengwu.

In: Angewandte Chemie - International Edition, Vol. 39, No. 3, 04.02.2000, p. 527-530.

Research output: Contribution to journal › Article

Pan, L, Huang, X, Li, J, Wu, Y & Zheng, N 2000, 'Novel single- and double-layer and three-dimensional structures of rare- Earth metal coordination polymers: The effect of lanthanide contraction and acidity control in crystal structure formation', Angewandte Chemie - International Edition, vol. 39, no. 3, pp. 527-530. https://doi.org/10.1002/(SICI)1521-3773(20000204)39:3<527::AID-ANIE527>3.0.CO;2-W

Pan L, Huang X, Li J, Wu Y, Zheng N. Novel single- and double-layer and three-dimensional structures of rare- Earth metal coordination polymers: The effect of lanthanide contraction and acidity control in crystal structure formation. Angewandte Chemie - International Edition. 2000 Feb 4;39(3):527-530. https://doi.org/10.1002/(SICI)1521-3773(20000204)39:3<527::AID-ANIE527>3.0.CO;2-W

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10.1002/(SICI)1521-3773(20000204)39:3<527::AID-ANIE527>3.0.CO;2-W