Abstract
Lanthanide atom sizes (the lanthanide contraction) directly control the type of structure formed by the coordination of a single multidentate ligand, 3,5-pyrazoledicarboxylic acid (H3pdc). Single-layer, double-layer ([Eu2(Hpdc)3(H2O)6], see picture), and three-dimensional networks were found. Control of the reaction pH plays a key role in the structure formation in this system.
| Original language | English |
|---|---|
| Pages (from-to) | 527-530 |
| Number of pages | 4 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 39 |
| Issue number | 3 |
| DOIs | |
| Publication status | Published - Feb 4 2000 |
Keywords
- Coordination modes
- Hydrothermal synthesis
- Lanthanides
- Rare-earth compounds
ASJC Scopus subject areas
- Catalysis
- Chemistry(all)
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Pan, L., Huang, X., Li, J., Wu, Y., & Zheng, N. (2000). Novel single- and double-layer and three-dimensional structures of rare- Earth metal coordination polymers: The effect of lanthanide contraction and acidity control in crystal structure formation. Angewandte Chemie - International Edition, 39(3), 527-530. https://doi.org/10.1002/(SICI)1521-3773(20000204)39:3<527::AID-ANIE527>3.0.CO;2-W