TY - JOUR
T1 - Novel single- and double-layer and three-dimensional structures of rare- Earth metal coordination polymers
T2 - The effect of lanthanide contraction and acidity control in crystal structure formation
AU - Pan, Long
AU - Huang, Xiaoying
AU - Li, Jing
AU - Wu, Yonggang
AU - Zheng, Nengwu
PY - 2000/2/4
Y1 - 2000/2/4
N2 - Lanthanide atom sizes (the lanthanide contraction) directly control the type of structure formed by the coordination of a single multidentate ligand, 3,5-pyrazoledicarboxylic acid (H3pdc). Single-layer, double-layer ([Eu2(Hpdc)3(H2O)6], see picture), and three-dimensional networks were found. Control of the reaction pH plays a key role in the structure formation in this system.
AB - Lanthanide atom sizes (the lanthanide contraction) directly control the type of structure formed by the coordination of a single multidentate ligand, 3,5-pyrazoledicarboxylic acid (H3pdc). Single-layer, double-layer ([Eu2(Hpdc)3(H2O)6], see picture), and three-dimensional networks were found. Control of the reaction pH plays a key role in the structure formation in this system.
KW - Coordination modes
KW - Hydrothermal synthesis
KW - Lanthanides
KW - Rare-earth compounds
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U2 - 10.1002/(SICI)1521-3773(20000204)39:3<527::AID-ANIE527>3.0.CO;2-W
DO - 10.1002/(SICI)1521-3773(20000204)39:3<527::AID-ANIE527>3.0.CO;2-W
M3 - Article
AN - SCOPUS:0034603136
VL - 39
SP - 527
EP - 530
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 3
ER -