Novel single- and double-layer and three-dimensional structures of rare- Earth metal coordination polymers

The effect of lanthanide contraction and acidity control in crystal structure formation

Long Pan, Xiaoying Huang, Jing Li, Yonggang Wu, Nengwu Zheng

Research output: Contribution to journal › Article

436 Citations (Scopus)

Abstract

Lanthanide atom sizes (the lanthanide contraction) directly control the type of structure formed by the coordination of a single multidentate ligand, 3,5-pyrazoledicarboxylic acid (H3pdc). Single-layer, double-layer ([Eu2(Hpdc)3(H2O)6], see picture), and three-dimensional networks were found. Control of the reaction pH plays a key role in the structure formation in this system.

Original languageEnglish
Pages (from-to)527-530
Number of pages4
JournalAngewandte Chemie - International Edition
Volume39
Issue number3
DOIs
Publication statusPublished - Feb 4 2000

Fingerprint

Rare Earth Metals
Lanthanoid Series Elements
Rare earth elements
Acidity
Rare earths
Polymers
Crystal structure
Metals
Ligands
Atoms
Acids

Keywords

  • Coordination modes
  • Hydrothermal synthesis
  • Lanthanides
  • Rare-earth compounds

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Novel single- and double-layer and three-dimensional structures of rare- Earth metal coordination polymers : The effect of lanthanide contraction and acidity control in crystal structure formation. / Pan, Long; Huang, Xiaoying; Li, Jing; Wu, Yonggang; Zheng, Nengwu.

In: Angewandte Chemie - International Edition, Vol. 39, No. 3, 04.02.2000, p. 527-530.

Research output: Contribution to journal › Article

Pan, L, Huang, X, Li, J, Wu, Y & Zheng, N 2000, 'Novel single- and double-layer and three-dimensional structures of rare- Earth metal coordination polymers: The effect of lanthanide contraction and acidity control in crystal structure formation', Angewandte Chemie - International Edition, vol. 39, no. 3, pp. 527-530. https://doi.org/10.1002/(SICI)1521-3773(20000204)39:3<527::AID-ANIE527>3.0.CO;2-W
Pan L, Huang X, Li J, Wu Y, Zheng N. Novel single- and double-layer and three-dimensional structures of rare- Earth metal coordination polymers: The effect of lanthanide contraction and acidity control in crystal structure formation. Angewandte Chemie - International Edition. 2000 Feb 4;39(3):527-530. https://doi.org/10.1002/(SICI)1521-3773(20000204)39:3<527::AID-ANIE527>3.0.CO;2-W
Pan, Long ; Huang, Xiaoying ; Li, Jing ; Wu, Yonggang ; Zheng, Nengwu. / Novel single- and double-layer and three-dimensional structures of rare- Earth metal coordination polymers : The effect of lanthanide contraction and acidity control in crystal structure formation. In: Angewandte Chemie - International Edition. 2000 ; Vol. 39, No. 3. pp. 527-530.
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