Abstract
Lanthanide atom sizes (the lanthanide contraction) directly control the type of structure formed by the coordination of a single multidentate ligand, 3,5-pyrazoledicarboxylic acid (H3pdc). Single-layer, double-layer ([Eu2(Hpdc)3(H2O)6], see picture), and three-dimensional networks were found. Control of the reaction pH plays a key role in the structure formation in this system.
| Original language | English |
|---|---|
| Pages (from-to) | 527-530 |
| Number of pages | 4 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 39 |
| Issue number | 3 |
| DOIs | |
| Publication status | Published - Feb 4 2000 |
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Keywords
- Coordination modes
- Hydrothermal synthesis
- Lanthanides
- Rare-earth compounds
ASJC Scopus subject areas
- Chemistry(all)
Cite this
Novel single- and double-layer and three-dimensional structures of rare- Earth metal coordination polymers : The effect of lanthanide contraction and acidity control in crystal structure formation. / Pan, Long; Huang, Xiaoying; Li, Jing; Wu, Yonggang; Zheng, Nengwu.
In: Angewandte Chemie - International Edition, Vol. 39, No. 3, 04.02.2000, p. 527-530.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Novel single- and double-layer and three-dimensional structures of rare- Earth metal coordination polymers
T2 - The effect of lanthanide contraction and acidity control in crystal structure formation
AU - Pan, Long
AU - Huang, Xiaoying
AU - Li, Jing
AU - Wu, Yonggang
AU - Zheng, Nengwu
PY - 2000/2/4
Y1 - 2000/2/4
N2 - Lanthanide atom sizes (the lanthanide contraction) directly control the type of structure formed by the coordination of a single multidentate ligand, 3,5-pyrazoledicarboxylic acid (H3pdc). Single-layer, double-layer ([Eu2(Hpdc)3(H2O)6], see picture), and three-dimensional networks were found. Control of the reaction pH plays a key role in the structure formation in this system.
AB - Lanthanide atom sizes (the lanthanide contraction) directly control the type of structure formed by the coordination of a single multidentate ligand, 3,5-pyrazoledicarboxylic acid (H3pdc). Single-layer, double-layer ([Eu2(Hpdc)3(H2O)6], see picture), and three-dimensional networks were found. Control of the reaction pH plays a key role in the structure formation in this system.
KW - Coordination modes
KW - Hydrothermal synthesis
KW - Lanthanides
KW - Rare-earth compounds
UR - http://www.scopus.com/inward/record.url?scp=0034603136&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0034603136&partnerID=8YFLogxK
U2 - 10.1002/(SICI)1521-3773(20000204)39:3<527::AID-ANIE527>3.0.CO;2-W
DO - 10.1002/(SICI)1521-3773(20000204)39:3<527::AID-ANIE527>3.0.CO;2-W
M3 - Article
AN - SCOPUS:0034603136
VL - 39
SP - 527
EP - 530
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 3
ER -