Nuclear Magnetic Resonance Study of Structural Dynamics in μ-Carbonyl-bis-μ-stannylene-diiron Hexacarbonyl Clusters

Gregory W. Grynkewich, Tobin J. Marks

Research output: Contribution to journalArticlepeer-review

26 Citations (Scopus)

Abstract

The compound μ-(C6H5)(CH3)Sn]2Fe2(CO)7 was synthesized to differentiate bridge deformation from iron-tin bond cleavage in R group interchange processes of stereochemically nonrigid [μ-R2Sn]2Fe2(CO)7 complexes. It is found from proton NMR studies that both processes can occur, the former with ΔG‡ = 11.8 ± 0.6 kcal/mol (298 K) and the latter with ΔG‡ = 19.2 ± 0.9 kcal/mol (298 K). The bridge deformation in the related, more soluble molecule [(n-C4H9)2Sn]2Fe2(CO)7 occurs with simultaneous, stereospecific interchange of bridge and terminal carbonyl ligands, as monitored by 13C NMR spectra. The complex [(C6H5)(CH3)SnFe(CO)4]2 exists in two isomeric forms which interconvert in solution with ΔG‡ = 25.5 ± 0.7 kcal/mol (298 K). The iron-tin bond cleavages are proposed to yield R2Sn→Fe stannylene intermediates.

Original languageEnglish
Pages (from-to)1307-1314
Number of pages8
JournalInorganic Chemistry
Volume15
Issue number6
DOIs
Publication statusPublished - Jun 1 1976

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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