Octacyanometallate qubit candidates

Tyler J. Pearson, Daniel W. Laorenza, Matthew D. Krzyaniak, Michael R Wasielewski, Danna E. Freedman

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

We report the temperature dependence of the spin dynamics of the octacyanometallates [Mo(CN)8]3- and [W(CN)8]3-. At 5 K, these complexes display remarkably long spin-lattice relaxation times of 1.05 s, and 0.63 s, respectively. We probe the contributing factors to the spin relaxation and demonstrate the impact of spin-orbit coupling as a handle to tune vibrationally mediated spin-lattice relaxation.

Original languageEnglish
Pages (from-to)11744-11748
Number of pages5
JournalDalton Transactions
Volume47
Issue number34
DOIs
Publication statusPublished - Jan 1 2018

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Spin-lattice relaxation
Spin dynamics
Relaxation time
Orbits
Temperature

ASJC Scopus subject areas

  • Inorganic Chemistry

Cite this

Pearson, T. J., Laorenza, D. W., Krzyaniak, M. D., Wasielewski, M. R., & Freedman, D. E. (2018). Octacyanometallate qubit candidates. Dalton Transactions, 47(34), 11744-11748. https://doi.org/10.1039/c8dt02312c

Octacyanometallate qubit candidates. / Pearson, Tyler J.; Laorenza, Daniel W.; Krzyaniak, Matthew D.; Wasielewski, Michael R; Freedman, Danna E.

In: Dalton Transactions, Vol. 47, No. 34, 01.01.2018, p. 11744-11748.

Research output: Contribution to journalArticle

Pearson, TJ, Laorenza, DW, Krzyaniak, MD, Wasielewski, MR & Freedman, DE 2018, 'Octacyanometallate qubit candidates', Dalton Transactions, vol. 47, no. 34, pp. 11744-11748. https://doi.org/10.1039/c8dt02312c
Pearson TJ, Laorenza DW, Krzyaniak MD, Wasielewski MR, Freedman DE. Octacyanometallate qubit candidates. Dalton Transactions. 2018 Jan 1;47(34):11744-11748. https://doi.org/10.1039/c8dt02312c
Pearson, Tyler J. ; Laorenza, Daniel W. ; Krzyaniak, Matthew D. ; Wasielewski, Michael R ; Freedman, Danna E. / Octacyanometallate qubit candidates. In: Dalton Transactions. 2018 ; Vol. 47, No. 34. pp. 11744-11748.
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