Octacyanometallate qubit candidates

Tyler J. Pearson; Daniel W. Laorenza; Matthew D. Krzyaniak; Michael R. Wasielewski; Danna E. Freedman

doi:10.1039/c8dt02312c

Octacyanometallate qubit candidates

Tyler J. Pearson, Daniel W. Laorenza, Matthew D. Krzyaniak, Michael R. Wasielewski, Danna E. Freedman

Northwestern University

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

We report the temperature dependence of the spin dynamics of the octacyanometallates [Mo(CN)₈]^3- and [W(CN)₈]^3-. At 5 K, these complexes display remarkably long spin-lattice relaxation times of 1.05 s, and 0.63 s, respectively. We probe the contributing factors to the spin relaxation and demonstrate the impact of spin-orbit coupling as a handle to tune vibrationally mediated spin-lattice relaxation.

Original language	English
Pages (from-to)	11744-11748
Number of pages	5
Journal	Dalton Transactions
Volume	47
Issue number	34
DOIs	https://doi.org/10.1039/c8dt02312c
Publication status	Published - Jan 1 2018

ASJC Scopus subject areas

Inorganic Chemistry

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10.1039/c8dt02312c

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abstract = "We report the temperature dependence of the spin dynamics of the octacyanometallates [Mo(CN)8]3- and [W(CN)8]3-. At 5 K, these complexes display remarkably long spin-lattice relaxation times of 1.05 s, and 0.63 s, respectively. We probe the contributing factors to the spin relaxation and demonstrate the impact of spin-orbit coupling as a handle to tune vibrationally mediated spin-lattice relaxation.",

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AU - Pearson, Tyler J.

AU - Laorenza, Daniel W.

AU - Krzyaniak, Matthew D.

AU - Wasielewski, Michael R.

AU - Freedman, Danna E.

PY - 2018/1/1

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AB - We report the temperature dependence of the spin dynamics of the octacyanometallates [Mo(CN)8]3- and [W(CN)8]3-. At 5 K, these complexes display remarkably long spin-lattice relaxation times of 1.05 s, and 0.63 s, respectively. We probe the contributing factors to the spin relaxation and demonstrate the impact of spin-orbit coupling as a handle to tune vibrationally mediated spin-lattice relaxation.

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