Oligoselenophenes (n and p Type): Synthesis and Properties

B. Mondal, M. Bendikov, U. Kanti Roy

Research output: Contribution to journalArticle

Abstract

An array of semiconducting oligoselenophenes (n and p types), up to hexamer units, has been synthesized by the double Stille coupling methods using tetrakis(triphenylphosphine)palladium(0) as a catalyst. A series of semiconducting oligomers (n and p types) containing mixed hetero-units (hexamers of thiophene and selenophene) have been also synthesized using the Stille coupling reaction. Their thermal properties are systematically studied and compared with those of π-conjugated thiophene based oligomers using DSC and TGA. The field-effect mobility of synthesized n and p type oligomers is analyzed.

Original languageEnglish
Pages (from-to)1911-1922
Number of pages12
JournalRussian Journal of General Chemistry
Volume89
Issue number9
DOIs
Publication statusPublished - Sep 1 2019

Fingerprint

Oligomers
Thiophenes
Palladium
Thermodynamic properties
Catalysts

Keywords

  • n and p type oligomers
  • oligomer
  • oligoselenophene
  • selenophene
  • sexiselenophenes
  • Stille coupling

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Oligoselenophenes (n and p Type) : Synthesis and Properties. / Mondal, B.; Bendikov, M.; Kanti Roy, U.

In: Russian Journal of General Chemistry, Vol. 89, No. 9, 01.09.2019, p. 1911-1922.

Research output: Contribution to journalArticle

Mondal, B. ; Bendikov, M. ; Kanti Roy, U. / Oligoselenophenes (n and p Type) : Synthesis and Properties. In: Russian Journal of General Chemistry. 2019 ; Vol. 89, No. 9. pp. 1911-1922.
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