Abstract
An analytic perturbation series procedure is developed for evaluating transition amplitudes in an adiabatic basis throughout the asymptotic region of a molecular collision process described in Delves coordinates. This procedure is used in conjunction with the classical path method in a treatment of collinear atom-harmonic oscillator collisions. The importance of the new procedure in the application of the classical path method to reactive scattering is discussed.
| Original language | English |
|---|---|
| Pages (from-to) | 3132-3138 |
| Number of pages | 7 |
| Journal | Journal of Chemical Physics |
| Volume | 82 |
| Issue number | 7 |
| Publication status | Published - 1984 |
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ASJC Scopus subject areas
- Atomic and Molecular Physics, and Optics
Cite this
On the classical path method using Delves coordinates : Asymptotic solution for time-dependent amplitudes. / Gilbert, R. D.; Muckerman, James.
In: Journal of Chemical Physics, Vol. 82, No. 7, 1984, p. 3132-3138.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - On the classical path method using Delves coordinates
T2 - Asymptotic solution for time-dependent amplitudes
AU - Gilbert, R. D.
AU - Muckerman, James
PY - 1984
Y1 - 1984
N2 - An analytic perturbation series procedure is developed for evaluating transition amplitudes in an adiabatic basis throughout the asymptotic region of a molecular collision process described in Delves coordinates. This procedure is used in conjunction with the classical path method in a treatment of collinear atom-harmonic oscillator collisions. The importance of the new procedure in the application of the classical path method to reactive scattering is discussed.
AB - An analytic perturbation series procedure is developed for evaluating transition amplitudes in an adiabatic basis throughout the asymptotic region of a molecular collision process described in Delves coordinates. This procedure is used in conjunction with the classical path method in a treatment of collinear atom-harmonic oscillator collisions. The importance of the new procedure in the application of the classical path method to reactive scattering is discussed.
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UR - http://www.scopus.com/inward/citedby.url?scp=36549097899&partnerID=8YFLogxK
M3 - Article
VL - 82
SP - 3132
EP - 3138
JO - Journal of Chemical Physics
JF - Journal of Chemical Physics
SN - 0021-9606
IS - 7
ER -