Abstract
An analytic perturbation series procedure is developed for evaluating transition amplitudes in an adiabatic basis throughout the asymptotic region of a molecular collision process described in Delves coordinates. This procedure is used in conjunction with the classical path method in a treatment of collinear atom-harmonic oscillator collisions. The importance of the new procedure in the application of the classical path method to reactive scattering is discussed.
| Original language | English |
|---|---|
| Pages (from-to) | 3132-3138 |
| Number of pages | 7 |
| Journal | The Journal of Chemical Physics |
| Volume | 82 |
| Issue number | 7 |
| Publication status | Published - Dec 1 1984 |
ASJC Scopus subject areas
- Physics and Astronomy(all)
- Physical and Theoretical Chemistry
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Gilbert, R. D., & Muckerman, J. T. (1984). On the classical path method using Delves coordinates: Asymptotic solution for time-dependent amplitudes. The Journal of Chemical Physics, 82(7), 3132-3138.