On the classical path method using Delves coordinates: Asymptotic solution for time-dependent amplitudes

R. D. Gilbert, J. T. Muckerman

Research output: Contribution to journalArticlepeer-review

6 Citations (Scopus)

Abstract

An analytic perturbation series procedure is developed for evaluating transition amplitudes in an adiabatic basis throughout the asymptotic region of a molecular collision process described in Delves coordinates. This procedure is used in conjunction with the classical path method in a treatment of collinear atom-harmonic oscillator collisions. The importance of the new procedure in the application of the classical path method to reactive scattering is discussed.

Original languageEnglish
Pages (from-to)3132-3138
Number of pages7
JournalThe Journal of Chemical Physics
Volume82
Issue number7
Publication statusPublished - Dec 1 1984

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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