Abstract
An analytic perturbation series procedure is developed for evaluating transition amplitudes in an adiabatic basis throughout the asymptotic region of a molecular collision process described in Delves coordinates. This procedure is used in conjunction with the classical path method in a treatment of collinear atom-harmonic oscillator collisions. The importance of the new procedure in the application of the classical path method to reactive scattering is discussed.
| Original language | English |
|---|---|
| Pages (from-to) | 3132-3138 |
| Number of pages | 7 |
| Journal | Journal of Chemical Physics |
| Volume | 82 |
| Issue number | 7 |
| Publication status | Published - 1984 |
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ASJC Scopus subject areas
- Atomic and Molecular Physics, and Optics
Cite this
Gilbert, R. D., & Muckerman, J. (1984). On the classical path method using Delves coordinates: Asymptotic solution for time-dependent amplitudes. Journal of Chemical Physics, 82(7), 3132-3138.