TY - JOUR
T1 - Open-framework oxysulfide based on the supertetrahedral [In4Sn16O10S34]12- cluster and efficient sequestration of heavy metals
AU - Zhang, Xian Ming
AU - Sarma, Debajit
AU - Wu, Ya Qin
AU - Wang, Li
AU - Ning, Zhi Xue
AU - Zhang, Fu Qiang
AU - Kanatzidis, Mercouri G.
N1 - Funding Information:
This work was financially supported by 10,000 Talent Plan, NSFC (2095101, 21371147, 21365021), the Ministry of Education of China (no. IRT1156), and XJOYF (grant no. 2013711009). At Northwestern this research was supported by the National Science Foundation (Grant DMR-1410169).
PY - 2016/5/4
Y1 - 2016/5/4
N2 - The new ion-exchange oxy-sulfide material has a three-dimensional open framework comprising the pseudo-T4 supertetrahedral [In4Sn16O10S34]12- cluster. This material has large pores and is a fast ion exchanger. It exhibits high selectivity in sequestering heavy metal ions from aqueous solutions including solutions containing heavy concentrations of sodium, calcium, ammonium, magnesium, zinc, carbonate, phosphate, and acetate ions. Moreover, the ion-exchange efficiency in competitive ionexchange experiments involving mixtures of metal ions is significantly higher than for solutions of single metal ions.
AB - The new ion-exchange oxy-sulfide material has a three-dimensional open framework comprising the pseudo-T4 supertetrahedral [In4Sn16O10S34]12- cluster. This material has large pores and is a fast ion exchanger. It exhibits high selectivity in sequestering heavy metal ions from aqueous solutions including solutions containing heavy concentrations of sodium, calcium, ammonium, magnesium, zinc, carbonate, phosphate, and acetate ions. Moreover, the ion-exchange efficiency in competitive ionexchange experiments involving mixtures of metal ions is significantly higher than for solutions of single metal ions.
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U2 - 10.1021/jacs.6b02959
DO - 10.1021/jacs.6b02959
M3 - Article
AN - SCOPUS:84968817580
VL - 138
SP - 5543
EP - 5546
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
SN - 0002-7863
IS - 17
ER -