Open-framework oxysulfide based on the supertetrahedral [In4Sn16O10S34]12- cluster and efficient sequestration of heavy metals

Xian Ming Zhang; Debajit Sarma; Ya Qin Wu; Li Wang; Zhi Xue Ning; Fu Qiang Zhang; Mercouri G. Kanatzidis

doi:10.1021/jacs.6b02959

Open-framework oxysulfide based on the supertetrahedral [In₄Sn₁₆O₁₀S₃₄]^12- cluster and efficient sequestration of heavy metals

Xian Ming Zhang, Debajit Sarma, Ya Qin Wu, Li Wang, Zhi Xue Ning, Fu Qiang Zhang, Mercouri G. Kanatzidis

Northwestern University

Research output: Contribution to journal › Article

53 Citations (Scopus)

Abstract

The new ion-exchange oxy-sulfide material has a three-dimensional open framework comprising the pseudo-T4 supertetrahedral [In₄Sn₁₆O₁₀S₃₄]^12- cluster. This material has large pores and is a fast ion exchanger. It exhibits high selectivity in sequestering heavy metal ions from aqueous solutions including solutions containing heavy concentrations of sodium, calcium, ammonium, magnesium, zinc, carbonate, phosphate, and acetate ions. Moreover, the ion-exchange efficiency in competitive ionexchange experiments involving mixtures of metal ions is significantly higher than for solutions of single metal ions.

Original language	English
Pages (from-to)	5543-5546
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	138
Issue number	17
DOIs	https://doi.org/10.1021/jacs.6b02959
Publication status	Published - May 4 2016

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ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

Cite this

Zhang, X. M., Sarma, D., Wu, Y. Q., Wang, L., Ning, Z. X., Zhang, F. Q., & Kanatzidis, M. G. (2016). Open-framework oxysulfide based on the supertetrahedral [In₄Sn₁₆O₁₀S₃₄]^12- cluster and efficient sequestration of heavy metals. Journal of the American Chemical Society, 138(17), 5543-5546. https://doi.org/10.1021/jacs.6b02959

Open-framework oxysulfide based on the supertetrahedral [In₄Sn₁₆O₁₀S₃₄]^12- cluster and efficient sequestration of heavy metals. / Zhang, Xian Ming; Sarma, Debajit; Wu, Ya Qin; Wang, Li; Ning, Zhi Xue; Zhang, Fu Qiang; Kanatzidis, Mercouri G.

In: Journal of the American Chemical Society, Vol. 138, No. 17, 04.05.2016, p. 5543-5546.

Research output: Contribution to journal › Article

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Access to Document

10.1021/jacs.6b02959