Abstract
The new ion-exchange oxy-sulfide material has a three-dimensional open framework comprising the pseudo-T4 supertetrahedral [In4Sn16O10S34]12- cluster. This material has large pores and is a fast ion exchanger. It exhibits high selectivity in sequestering heavy metal ions from aqueous solutions including solutions containing heavy concentrations of sodium, calcium, ammonium, magnesium, zinc, carbonate, phosphate, and acetate ions. Moreover, the ion-exchange efficiency in competitive ionexchange experiments involving mixtures of metal ions is significantly higher than for solutions of single metal ions.
| Original language | English |
|---|---|
| Pages (from-to) | 5543-5546 |
| Number of pages | 4 |
| Journal | Journal of the American Chemical Society |
| Volume | 138 |
| Issue number | 17 |
| DOIs | |
| Publication status | Published - May 4 2016 |
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ASJC Scopus subject areas
- Chemistry(all)
- Catalysis
- Biochemistry
- Colloid and Surface Chemistry
Cite this
Open-framework oxysulfide based on the supertetrahedral [In4Sn16O10S34]12- cluster and efficient sequestration of heavy metals. / Zhang, Xian Ming; Sarma, Debajit; Wu, Ya Qin; Wang, Li; Ning, Zhi Xue; Zhang, Fu Qiang; Kanatzidis, Mercouri G.
In: Journal of the American Chemical Society, Vol. 138, No. 17, 04.05.2016, p. 5543-5546.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Open-framework oxysulfide based on the supertetrahedral [In4Sn16O10S34]12- cluster and efficient sequestration of heavy metals
AU - Zhang, Xian Ming
AU - Sarma, Debajit
AU - Wu, Ya Qin
AU - Wang, Li
AU - Ning, Zhi Xue
AU - Zhang, Fu Qiang
AU - Kanatzidis, Mercouri G
PY - 2016/5/4
Y1 - 2016/5/4
N2 - The new ion-exchange oxy-sulfide material has a three-dimensional open framework comprising the pseudo-T4 supertetrahedral [In4Sn16O10S34]12- cluster. This material has large pores and is a fast ion exchanger. It exhibits high selectivity in sequestering heavy metal ions from aqueous solutions including solutions containing heavy concentrations of sodium, calcium, ammonium, magnesium, zinc, carbonate, phosphate, and acetate ions. Moreover, the ion-exchange efficiency in competitive ionexchange experiments involving mixtures of metal ions is significantly higher than for solutions of single metal ions.
AB - The new ion-exchange oxy-sulfide material has a three-dimensional open framework comprising the pseudo-T4 supertetrahedral [In4Sn16O10S34]12- cluster. This material has large pores and is a fast ion exchanger. It exhibits high selectivity in sequestering heavy metal ions from aqueous solutions including solutions containing heavy concentrations of sodium, calcium, ammonium, magnesium, zinc, carbonate, phosphate, and acetate ions. Moreover, the ion-exchange efficiency in competitive ionexchange experiments involving mixtures of metal ions is significantly higher than for solutions of single metal ions.
UR - http://www.scopus.com/inward/record.url?scp=84968817580&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84968817580&partnerID=8YFLogxK
U2 - 10.1021/jacs.6b02959
DO - 10.1021/jacs.6b02959
M3 - Article
VL - 138
SP - 5543
EP - 5546
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
SN - 0002-7863
IS - 17
ER -