Open-framework oxysulfide based on the supertetrahedral [In4Sn16O10S34]12- cluster and efficient sequestration of heavy metals

Xian Ming Zhang; Debajit Sarma; Ya Qin Wu; Li Wang; Zhi Xue Ning; Fu Qiang Zhang; Mercouri G. Kanatzidis

doi:10.1021/jacs.6b02959

Open-framework oxysulfide based on the supertetrahedral [In₄Sn₁₆O₁₀S₃₄]^12- cluster and efficient sequestration of heavy metals

Xian Ming Zhang, Debajit Sarma, Ya Qin Wu, Li Wang, Zhi Xue Ning, Fu Qiang Zhang, Mercouri G. Kanatzidis

Northwestern University

Research output: Contribution to journal › Article › peer-review

56 Citations (Scopus)

Abstract

The new ion-exchange oxy-sulfide material has a three-dimensional open framework comprising the pseudo-T4 supertetrahedral [In₄Sn₁₆O₁₀S₃₄]^12- cluster. This material has large pores and is a fast ion exchanger. It exhibits high selectivity in sequestering heavy metal ions from aqueous solutions including solutions containing heavy concentrations of sodium, calcium, ammonium, magnesium, zinc, carbonate, phosphate, and acetate ions. Moreover, the ion-exchange efficiency in competitive ionexchange experiments involving mixtures of metal ions is significantly higher than for solutions of single metal ions.

Original language	English
Pages (from-to)	5543-5546
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	138
Issue number	17
DOIs	https://doi.org/10.1021/jacs.6b02959
Publication status	Published - May 4 2016

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

Access to Document

10.1021/jacs.6b02959

Fingerprint Dive into the research topics of 'Open-framework oxysulfide based on the supertetrahedral [In4Sn16O10S34]12- cluster and efficient sequestration of heavy metals'. Together they form a unique fingerprint.

Cite this

Open-framework oxysulfide based on the supertetrahedral [In₄Sn₁₆O₁₀S₃₄]^12- cluster and efficient sequestration of heavy metals. / Zhang, Xian Ming; Sarma, Debajit; Wu, Ya Qin; Wang, Li; Ning, Zhi Xue; Zhang, Fu Qiang; Kanatzidis, Mercouri G.

In: Journal of the American Chemical Society, Vol. 138, No. 17, 04.05.2016, p. 5543-5546.

Research output: Contribution to journal › Article › peer-review

@article{093c727079de4d8382639e3c12f110d1,

title = "Open-framework oxysulfide based on the supertetrahedral [In4Sn16O10S34]12- cluster and efficient sequestration of heavy metals",

abstract = "The new ion-exchange oxy-sulfide material has a three-dimensional open framework comprising the pseudo-T4 supertetrahedral [In4Sn16O10S34]12- cluster. This material has large pores and is a fast ion exchanger. It exhibits high selectivity in sequestering heavy metal ions from aqueous solutions including solutions containing heavy concentrations of sodium, calcium, ammonium, magnesium, zinc, carbonate, phosphate, and acetate ions. Moreover, the ion-exchange efficiency in competitive ionexchange experiments involving mixtures of metal ions is significantly higher than for solutions of single metal ions.",

author = "Zhang, {Xian Ming} and Debajit Sarma and Wu, {Ya Qin} and Li Wang and Ning, {Zhi Xue} and Zhang, {Fu Qiang} and Kanatzidis, {Mercouri G.}",

note = "Funding Information: This work was financially supported by 10,000 Talent Plan, NSFC (2095101, 21371147, 21365021), the Ministry of Education of China (no. IRT1156), and XJOYF (grant no. 2013711009). At Northwestern this research was supported by the National Science Foundation (Grant DMR-1410169).",

year = "2016",

month = may,

day = "4",

doi = "10.1021/jacs.6b02959",

language = "English",

volume = "138",

pages = "5543--5546",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "17",

}

TY - JOUR

T1 - Open-framework oxysulfide based on the supertetrahedral [In4Sn16O10S34]12- cluster and efficient sequestration of heavy metals

AU - Zhang, Xian Ming

AU - Sarma, Debajit

AU - Wu, Ya Qin

AU - Wang, Li

AU - Ning, Zhi Xue

AU - Zhang, Fu Qiang

AU - Kanatzidis, Mercouri G.

N1 - Funding Information: This work was financially supported by 10,000 Talent Plan, NSFC (2095101, 21371147, 21365021), the Ministry of Education of China (no. IRT1156), and XJOYF (grant no. 2013711009). At Northwestern this research was supported by the National Science Foundation (Grant DMR-1410169).

PY - 2016/5/4

Y1 - 2016/5/4

N2 - The new ion-exchange oxy-sulfide material has a three-dimensional open framework comprising the pseudo-T4 supertetrahedral [In4Sn16O10S34]12- cluster. This material has large pores and is a fast ion exchanger. It exhibits high selectivity in sequestering heavy metal ions from aqueous solutions including solutions containing heavy concentrations of sodium, calcium, ammonium, magnesium, zinc, carbonate, phosphate, and acetate ions. Moreover, the ion-exchange efficiency in competitive ionexchange experiments involving mixtures of metal ions is significantly higher than for solutions of single metal ions.

AB - The new ion-exchange oxy-sulfide material has a three-dimensional open framework comprising the pseudo-T4 supertetrahedral [In4Sn16O10S34]12- cluster. This material has large pores and is a fast ion exchanger. It exhibits high selectivity in sequestering heavy metal ions from aqueous solutions including solutions containing heavy concentrations of sodium, calcium, ammonium, magnesium, zinc, carbonate, phosphate, and acetate ions. Moreover, the ion-exchange efficiency in competitive ionexchange experiments involving mixtures of metal ions is significantly higher than for solutions of single metal ions.

UR - http://www.scopus.com/inward/record.url?scp=84968817580&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84968817580&partnerID=8YFLogxK

U2 - 10.1021/jacs.6b02959

DO - 10.1021/jacs.6b02959

M3 - Article

AN - SCOPUS:84968817580

VL - 138

SP - 5543

EP - 5546

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

SN - 0002-7863

IS - 17

ER -