Open-framework oxysulfide based on the supertetrahedral [In4Sn16O10S34]12- cluster and efficient sequestration of heavy metals

Xian Ming Zhang, Debajit Sarma, Ya Qin Wu, Li Wang, Zhi Xue Ning, Fu Qiang Zhang, Mercouri G Kanatzidis

Research output: Contribution to journalArticle

46 Citations (Scopus)

Abstract

The new ion-exchange oxy-sulfide material has a three-dimensional open framework comprising the pseudo-T4 supertetrahedral [In4Sn16O10S34]12- cluster. This material has large pores and is a fast ion exchanger. It exhibits high selectivity in sequestering heavy metal ions from aqueous solutions including solutions containing heavy concentrations of sodium, calcium, ammonium, magnesium, zinc, carbonate, phosphate, and acetate ions. Moreover, the ion-exchange efficiency in competitive ionexchange experiments involving mixtures of metal ions is significantly higher than for solutions of single metal ions.

Original languageEnglish
Pages (from-to)5543-5546
Number of pages4
JournalJournal of the American Chemical Society
Volume138
Issue number17
DOIs
Publication statusPublished - May 4 2016

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Heavy Metals
Heavy metals
Metal ions
Ions
Ion Exchange
Ion exchange
Ion exchangers
Zinc Acetate
Metals
Sulfides
Heavy ions
Ammonium Compounds
Heavy Ions
Magnesium
Carbonates
Calcium
Phosphates
Acetates
Zinc
Sodium

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

Open-framework oxysulfide based on the supertetrahedral [In4Sn16O10S34]12- cluster and efficient sequestration of heavy metals. / Zhang, Xian Ming; Sarma, Debajit; Wu, Ya Qin; Wang, Li; Ning, Zhi Xue; Zhang, Fu Qiang; Kanatzidis, Mercouri G.

In: Journal of the American Chemical Society, Vol. 138, No. 17, 04.05.2016, p. 5543-5546.

Research output: Contribution to journalArticle

Zhang, Xian Ming ; Sarma, Debajit ; Wu, Ya Qin ; Wang, Li ; Ning, Zhi Xue ; Zhang, Fu Qiang ; Kanatzidis, Mercouri G. / Open-framework oxysulfide based on the supertetrahedral [In4Sn16O10S34]12- cluster and efficient sequestration of heavy metals. In: Journal of the American Chemical Society. 2016 ; Vol. 138, No. 17. pp. 5543-5546.
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