Optical floating zone growth of β-BaB2O4 from a LiBa2B5O10-based solvent

Shilie Pan; Jared P. Smit; Courtney H. Lanier; Michael R. Marvel; Laurence D. Marks; Kenneth R. Poeppelmeier

doi:10.1021/cg0702232

Optical floating zone growth of β-BaB₂O₄ from a LiBa₂B₅O₁₀-based solvent

Shilie Pan, Jared P. Smit, Courtney H. Lanier, Michael R. Marvel, Laurence D. Marks, Kenneth R. Poeppelmeier

Northwestern University

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

Low-temperature barium metaborate β-BaB₂O₄ has been grown using a LiBa₂B₅O₁₀-based solvent in a four-mirror optical floating zone furnace with a traveling solvent zone configuration. The β-BaB₂O₄ rods grown are composed of several different crystal domains, ranging from 100 μm to 1 mm in diameter, and lithium, a component of the flux, was present only at the contaminant level. The technique demonstrates that thermal decomposition of the incongruently melting phase LiBa₂B₅O₁₀ can be used to grow β-BaB₂O₄.

Original language	English
Pages (from-to)	1561-1564
Number of pages	4
Journal	Crystal Growth and Design
Volume	7
Issue number	8
DOIs	https://doi.org/10.1021/cg0702232
Publication status	Published - Aug 1 2007

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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abstract = "Low-temperature barium metaborate β-BaB2O4 has been grown using a LiBa2B5O10-based solvent in a four-mirror optical floating zone furnace with a traveling solvent zone configuration. The β-BaB2O4 rods grown are composed of several different crystal domains, ranging from 100 μm to 1 mm in diameter, and lithium, a component of the flux, was present only at the contaminant level. The technique demonstrates that thermal decomposition of the incongruently melting phase LiBa2B5O10 can be used to grow β-BaB2O4.",

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AU - Smit, Jared P.

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AU - Marvel, Michael R.

AU - Marks, Laurence D.

AU - Poeppelmeier, Kenneth R.

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N2 - Low-temperature barium metaborate β-BaB2O4 has been grown using a LiBa2B5O10-based solvent in a four-mirror optical floating zone furnace with a traveling solvent zone configuration. The β-BaB2O4 rods grown are composed of several different crystal domains, ranging from 100 μm to 1 mm in diameter, and lithium, a component of the flux, was present only at the contaminant level. The technique demonstrates that thermal decomposition of the incongruently melting phase LiBa2B5O10 can be used to grow β-BaB2O4.

AB - Low-temperature barium metaborate β-BaB2O4 has been grown using a LiBa2B5O10-based solvent in a four-mirror optical floating zone furnace with a traveling solvent zone configuration. The β-BaB2O4 rods grown are composed of several different crystal domains, ranging from 100 μm to 1 mm in diameter, and lithium, a component of the flux, was present only at the contaminant level. The technique demonstrates that thermal decomposition of the incongruently melting phase LiBa2B5O10 can be used to grow β-BaB2O4.

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Optical floating zone growth of β-BaB₂O₄ from a LiBa₂B₅O₁₀-based solvent

Abstract

ASJC Scopus subject areas

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