Optical limiting and excited-state absorption in fullerene solutions and doped glasses

Duncan W. McBranch; Laura B. Smilowitz; V. Klimov; A. Koskelo; Jeanne M. Robinson; Ben R. Mattes; J. C. Hummelen; F. Wudl; James C. Withers; Nicholas F. Borrelli

doi:10.1117/12.228119

Optical limiting and excited-state absorption in fullerene solutions and doped glasses

Duncan W. McBranch, Laura B. Smilowitz, V. Klimov, A. Koskelo, Jeanne M. Robinson, Ben R. Mattes, J. C. Hummelen, F. Wudl, James C. Withers, Nicholas F. Borrelli

Los Alamos National Laboratory

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

15 Citations (Scopus)

Abstract

We report the ground-state and excited-state optical absorption spectra in the visible and near infrared for several substituted fullerenes and higher fullerenes in toluene solutions. Based on these measurements, broadband predictions of the optical limiting performance of these molecules can be deduced. These predictions are then tested in the wavelength range from 532 nm to 700 nm in intensity-dependent transmission measurements. We observe optical limiting in all fullerenes measured; higher fullerenes show the greatest potential for limiting in the near infrared (650 - 1000 nm), while substituted C₆₀ shows optimal limiting in the visible (450 - 700 nm). We observe dramatically reduced limiting for solid forms of C₆₀ (thin films and C₆₀-doped porous glasses), indicating that efficient optical limiting in fullerenes requires true molecular solutions.

Original language	English
Title of host publication	Proceedings of SPIE - The International Society for Optical Engineering
Publisher	Society of Photo-Optical Instrumentation Engineers
Pages	196-204
Number of pages	9
Volume	2530
ISBN (Print)	0819418897, 9780819418890
DOIs	https://doi.org/10.1117/12.228119
Publication status	Published - 1995
Event	Fullerenes and Photonics II - San Diego, CA, USA Duration: Jul 10 1995 → Jul 11 1995

Other

Other	Fullerenes and Photonics II
City	San Diego, CA, USA
Period	7/10/95 → 7/11/95

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Computer Science Applications
Applied Mathematics
Electrical and Electronic Engineering

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McBranch, D. W., Smilowitz, L. B., Klimov, V., Koskelo, A., Robinson, J. M., Mattes, B. R., Hummelen, J. C., Wudl, F., Withers, J. C., & Borrelli, N. F. (1995). Optical limiting and excited-state absorption in fullerene solutions and doped glasses. In Proceedings of SPIE - The International Society for Optical Engineering (Vol. 2530, pp. 196-204). Society of Photo-Optical Instrumentation Engineers. https://doi.org/10.1117/12.228119

Optical limiting and excited-state absorption in fullerene solutions and doped glasses. / McBranch, Duncan W.; Smilowitz, Laura B.; Klimov, V.; Koskelo, A.; Robinson, Jeanne M.; Mattes, Ben R.; Hummelen, J. C.; Wudl, F.; Withers, James C.; Borrelli, Nicholas F.

Proceedings of SPIE - The International Society for Optical Engineering. Vol. 2530 Society of Photo-Optical Instrumentation Engineers, 1995. p. 196-204.

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

McBranch, DW, Smilowitz, LB, Klimov, V, Koskelo, A, Robinson, JM, Mattes, BR, Hummelen, JC, Wudl, F, Withers, JC & Borrelli, NF 1995, Optical limiting and excited-state absorption in fullerene solutions and doped glasses. in Proceedings of SPIE - The International Society for Optical Engineering. vol. 2530, Society of Photo-Optical Instrumentation Engineers, pp. 196-204, Fullerenes and Photonics II, San Diego, CA, USA, 7/10/95. https://doi.org/10.1117/12.228119

McBranch, Duncan W. ; Smilowitz, Laura B. ; Klimov, V. ; Koskelo, A. ; Robinson, Jeanne M. ; Mattes, Ben R. ; Hummelen, J. C. ; Wudl, F. ; Withers, James C. ; Borrelli, Nicholas F. / Optical limiting and excited-state absorption in fullerene solutions and doped glasses. Proceedings of SPIE - The International Society for Optical Engineering. Vol. 2530 Society of Photo-Optical Instrumentation Engineers, 1995. pp. 196-204

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abstract = "We report the ground-state and excited-state optical absorption spectra in the visible and near infrared for several substituted fullerenes and higher fullerenes in toluene solutions. Based on these measurements, broadband predictions of the optical limiting performance of these molecules can be deduced. These predictions are then tested in the wavelength range from 532 nm to 700 nm in intensity-dependent transmission measurements. We observe optical limiting in all fullerenes measured; higher fullerenes show the greatest potential for limiting in the near infrared (650 - 1000 nm), while substituted C60 shows optimal limiting in the visible (450 - 700 nm). We observe dramatically reduced limiting for solid forms of C60 (thin films and C60-doped porous glasses), indicating that efficient optical limiting in fullerenes requires true molecular solutions.",

author = "McBranch, {Duncan W.} and Smilowitz, {Laura B.} and V. Klimov and A. Koskelo and Robinson, {Jeanne M.} and Mattes, {Ben R.} and Hummelen, {J. C.} and F. Wudl and Withers, {James C.} and Borrelli, {Nicholas F.}",

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AU - McBranch, Duncan W.

AU - Smilowitz, Laura B.

AU - Klimov, V.

AU - Koskelo, A.

AU - Robinson, Jeanne M.

AU - Mattes, Ben R.

AU - Hummelen, J. C.

AU - Wudl, F.

AU - Withers, James C.

AU - Borrelli, Nicholas F.

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N2 - We report the ground-state and excited-state optical absorption spectra in the visible and near infrared for several substituted fullerenes and higher fullerenes in toluene solutions. Based on these measurements, broadband predictions of the optical limiting performance of these molecules can be deduced. These predictions are then tested in the wavelength range from 532 nm to 700 nm in intensity-dependent transmission measurements. We observe optical limiting in all fullerenes measured; higher fullerenes show the greatest potential for limiting in the near infrared (650 - 1000 nm), while substituted C60 shows optimal limiting in the visible (450 - 700 nm). We observe dramatically reduced limiting for solid forms of C60 (thin films and C60-doped porous glasses), indicating that efficient optical limiting in fullerenes requires true molecular solutions.

AB - We report the ground-state and excited-state optical absorption spectra in the visible and near infrared for several substituted fullerenes and higher fullerenes in toluene solutions. Based on these measurements, broadband predictions of the optical limiting performance of these molecules can be deduced. These predictions are then tested in the wavelength range from 532 nm to 700 nm in intensity-dependent transmission measurements. We observe optical limiting in all fullerenes measured; higher fullerenes show the greatest potential for limiting in the near infrared (650 - 1000 nm), while substituted C60 shows optimal limiting in the visible (450 - 700 nm). We observe dramatically reduced limiting for solid forms of C60 (thin films and C60-doped porous glasses), indicating that efficient optical limiting in fullerenes requires true molecular solutions.

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