Abstract
For the first time, an increasing number of defects were introduced to the metal–organic framework UiO-66-NH2 in an attempt to understand the structure–activity trade-offs associated with toxic chemical removal. It was found that an optimum exists with moderate defects for toxic chemicals that react with the linker, whereas those that require hydrolysis at the secondary building unit performed better when more defects were introduced. The insights obtained through this work highlight the ability to dial-in appropriate material formulations, even within the same parent metal–organic framework, allowing for trade-offs between reaction efficiency and mass transfer.
| Original language | English |
|---|---|
| Pages (from-to) | 15913-15916 |
| Number of pages | 4 |
| Journal | Chemistry - A European Journal |
| Volume | 23 |
| Issue number | 63 |
| DOIs | |
| Publication status | Published - Nov 13 2017 |
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Keywords
- adsorption
- chemical warfare agents
- defects
- metal–organic frameworks
- toxic chemicals
ASJC Scopus subject areas
- Chemistry(all)
Cite this
Optimizing Toxic Chemical Removal through Defect-Induced UiO-66-NH2 Metal–Organic Framework. / Peterson, Gregory W.; Destefano, Matthew R.; Garibay, Sergio J.; Ploskonka, Ann; McEntee, Monica; Hall, Morgan; Karwacki, Christopher J.; Hupp, Joseph T; Farha, Omar K.
In: Chemistry - A European Journal, Vol. 23, No. 63, 13.11.2017, p. 15913-15916.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Optimizing Toxic Chemical Removal through Defect-Induced UiO-66-NH2 Metal–Organic Framework
AU - Peterson, Gregory W.
AU - Destefano, Matthew R.
AU - Garibay, Sergio J.
AU - Ploskonka, Ann
AU - McEntee, Monica
AU - Hall, Morgan
AU - Karwacki, Christopher J.
AU - Hupp, Joseph T
AU - Farha, Omar K.
PY - 2017/11/13
Y1 - 2017/11/13
N2 - For the first time, an increasing number of defects were introduced to the metal–organic framework UiO-66-NH2 in an attempt to understand the structure–activity trade-offs associated with toxic chemical removal. It was found that an optimum exists with moderate defects for toxic chemicals that react with the linker, whereas those that require hydrolysis at the secondary building unit performed better when more defects were introduced. The insights obtained through this work highlight the ability to dial-in appropriate material formulations, even within the same parent metal–organic framework, allowing for trade-offs between reaction efficiency and mass transfer.
AB - For the first time, an increasing number of defects were introduced to the metal–organic framework UiO-66-NH2 in an attempt to understand the structure–activity trade-offs associated with toxic chemical removal. It was found that an optimum exists with moderate defects for toxic chemicals that react with the linker, whereas those that require hydrolysis at the secondary building unit performed better when more defects were introduced. The insights obtained through this work highlight the ability to dial-in appropriate material formulations, even within the same parent metal–organic framework, allowing for trade-offs between reaction efficiency and mass transfer.
KW - adsorption
KW - chemical warfare agents
KW - defects
KW - metal–organic frameworks
KW - toxic chemicals
UR - http://www.scopus.com/inward/record.url?scp=85032698374&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85032698374&partnerID=8YFLogxK
U2 - 10.1002/chem.201704525
DO - 10.1002/chem.201704525
M3 - Article
AN - SCOPUS:85032698374
VL - 23
SP - 15913
EP - 15916
JO - Chemistry - A European Journal
JF - Chemistry - A European Journal
SN - 0947-6539
IS - 63
ER -