Organo-f-element catalysts for efficient and highly selective hydroalkoxylation and hydrothiolation

Charles J. Weiss, Tobin J. Marks

Research output: Contribution to journalArticle

136 Citations (Scopus)

Abstract

Lanthanide and actinide catalysts have made significant contributions to many areas of homogeneous catalysis with hydroelementation of C-C unsaturation being a notable area of success. In this Perspective, we review recent advances in f-element hydroelementation for highly selective hydroalkoxylation and hydrothiolation processes. As will be discussed, f-element hydroalkoxylation and hydrothiolation catalysts exhibit selectivities unobtainable by many late transition metal complexes. First, we review lanthanide-mediated hydroalkoxylation processes with mechanistic, thermodynamic, and kinetic considerations discussed, and then compare/contrast them with analogous C-N and C-P bond-forming transformations. In addition, computational studies are discussed which provide further insight into this transformation and the observed selectivities. Next, actinide-mediated alkyne hydrothiolation is reviewed with a similar discussion of reactivity, mechanism, and thermodynamics.

Original languageEnglish
Pages (from-to)6576-6588
Number of pages13
JournalDalton Transactions
Volume39
Issue number29
DOIs
Publication statusPublished - Jul 23 2010

ASJC Scopus subject areas

  • Inorganic Chemistry

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