ORGANOACTINIDE CARBONYLATION AND CARBOXYLATION CHEMISTRY. STRUCTURAL, ELECTRONIC, BOND ENERGY, AND PHOTOCHEMICAL EFFECTS ON MIGRATORY INSERTION IN THE TRIS(CYCLOPENTADIENYL)THORIUM HYDROCARBYL SERIES.

David C. Sonnenberger, Eric A. Mintz, Tobin J Marks

Research output: Contribution to journalArticle

80 Citations (Scopus)

Abstract

This work reports a synthetic and kinetic study of CO migratory insertion for a series of thorium hydrocarbyls. Under the conditions employed, the reaction was found to be first order in Th(C//5H//5)//3R and first order in CO. In the case of R equals i-C//3H//7 and CH//2Si(CH//3)//3, enolate rearrangement products were isolated and characterized. The relative rates of CO insertion reflect both steric and electronic effects; there is a significant correlation with experimentally determined Th-R bond disruption enthalpies.

Original languageEnglish
Pages (from-to)3484-3491
Number of pages8
JournalJournal of the American Chemical Society
Volume106
Issue number12
Publication statusPublished - Jan 1 1984

Fingerprint

Carboxylation
Thorium
Carbonylation
Carbon Monoxide
Enthalpy
Kinetics

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

@article{f28a71f2ffab4d4a981eeb625dec81be,
title = "ORGANOACTINIDE CARBONYLATION AND CARBOXYLATION CHEMISTRY. STRUCTURAL, ELECTRONIC, BOND ENERGY, AND PHOTOCHEMICAL EFFECTS ON MIGRATORY INSERTION IN THE TRIS(CYCLOPENTADIENYL)THORIUM HYDROCARBYL SERIES.",
abstract = "This work reports a synthetic and kinetic study of CO migratory insertion for a series of thorium hydrocarbyls. Under the conditions employed, the reaction was found to be first order in Th(C//5H//5)//3R and first order in CO. In the case of R equals i-C//3H//7 and CH//2Si(CH//3)//3, enolate rearrangement products were isolated and characterized. The relative rates of CO insertion reflect both steric and electronic effects; there is a significant correlation with experimentally determined Th-R bond disruption enthalpies.",
author = "Sonnenberger, {David C.} and Mintz, {Eric A.} and Marks, {Tobin J}",
year = "1984",
month = "1",
day = "1",
language = "English",
volume = "106",
pages = "3484--3491",
journal = "Journal of the American Chemical Society",
issn = "0002-7863",
publisher = "American Chemical Society",
number = "12",

}

TY - JOUR

T1 - ORGANOACTINIDE CARBONYLATION AND CARBOXYLATION CHEMISTRY. STRUCTURAL, ELECTRONIC, BOND ENERGY, AND PHOTOCHEMICAL EFFECTS ON MIGRATORY INSERTION IN THE TRIS(CYCLOPENTADIENYL)THORIUM HYDROCARBYL SERIES.

AU - Sonnenberger, David C.

AU - Mintz, Eric A.

AU - Marks, Tobin J

PY - 1984/1/1

Y1 - 1984/1/1

N2 - This work reports a synthetic and kinetic study of CO migratory insertion for a series of thorium hydrocarbyls. Under the conditions employed, the reaction was found to be first order in Th(C//5H//5)//3R and first order in CO. In the case of R equals i-C//3H//7 and CH//2Si(CH//3)//3, enolate rearrangement products were isolated and characterized. The relative rates of CO insertion reflect both steric and electronic effects; there is a significant correlation with experimentally determined Th-R bond disruption enthalpies.

AB - This work reports a synthetic and kinetic study of CO migratory insertion for a series of thorium hydrocarbyls. Under the conditions employed, the reaction was found to be first order in Th(C//5H//5)//3R and first order in CO. In the case of R equals i-C//3H//7 and CH//2Si(CH//3)//3, enolate rearrangement products were isolated and characterized. The relative rates of CO insertion reflect both steric and electronic effects; there is a significant correlation with experimentally determined Th-R bond disruption enthalpies.

UR - http://www.scopus.com/inward/record.url?scp=0021445320&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0021445320&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0021445320

VL - 106

SP - 3484

EP - 3491

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

SN - 0002-7863

IS - 12

ER -