Abstract
The organolanthanide complex (η5-Me5C5)2-SmCH(TMS) 2 serves as a precatalyst for the efficient and regiospecific hydroamination/cyclization of aliphatic and aromatic aminoalkynes RC≡C(CH2)nNH2 to yield the corresponding heterocycles RCH2C=N(CH2)n-1CH2. Kinetic and mechanistic evidence argues that the turnover-limiting step is intramolecular alkyne insertion into the Sm - N bond followed by rapid protonolysis of the resulting Sm - C bond.
| Original language | English |
|---|---|
| Pages (from-to) | 439-440 |
| Number of pages | 2 |
| Journal | Organometallics |
| Volume | 13 |
| Issue number | 2 |
| Publication status | Published - 1994 |
ASJC Scopus subject areas
- Inorganic Chemistry
- Organic Chemistry
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Li, Y., Fu, P. F., & Marks, T. J. (1994). Organolanthanide-catalyzed carbon-heteroatom bond formation. Observations on the facile, regiospecific cyclization of aminoalkynes. Organometallics, 13(2), 439-440.