Organolanthanide-centered hydroamination/cyclization of aminoolefins. Expedient oxidative access to catalytic cycles

Michel R. Gagné, Steven P. Nolan, Tobin J Marks

Research output: Contribution to journalArticle

159 Citations (Scopus)

Abstract

The readily accessible (Me5C5)2Sm and (Me5C5)2Sm(THF)2 catalyze the hydroamination/cyclization of a variety of aminoolefins. Mechanistic observations suggest that the active catalysts are trivalent organosamarium complexes.

Original languageEnglish
Pages (from-to)1716-1718
Number of pages3
JournalOrganometallics
Volume9
Issue number6
Publication statusPublished - 1990

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ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry

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