Organosilane effects on organotitanium-catalyzed styrene polymerization

Smruti B. Amin; Tobin J. Marks

doi:10.1021/om0700260

Organosilane effects on organotitanium-catalyzed styrene polymerization

Smruti B. Amin, Tobin J. Marks

Northwestern University

Research output: Contribution to journal › Article

12 Citations (Scopus)

Abstract

Organosilane reagents are introduced into organotitanium-mediated styrene polymerizations to produce atactic polystyrene with high activities (up to 10⁶ g polymer/(mol Ti·h)) and narrow polydispersities. Previously recognized CGCTiMe₂ systems having marginal styrene homopolymerization activity are shown to be up to 3 orders of magnitude more active for styrene homopolymerization upon addition of organosilane.

Original language	English
Pages (from-to)	2960-2963
Number of pages	4
Journal	Organometallics
Volume	26
Issue number	12
DOIs	https://doi.org/10.1021/om0700260
Publication status	Published - Jun 4 2007

Fingerprint

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

Cite this

Amin, S. B., & Marks, T. J. (2007). Organosilane effects on organotitanium-catalyzed styrene polymerization. Organometallics, 26(12), 2960-2963. https://doi.org/10.1021/om0700260

@article{5472863d1a09435cbeb7ada411cd7239,

title = "Organosilane effects on organotitanium-catalyzed styrene polymerization",

abstract = "Organosilane reagents are introduced into organotitanium-mediated styrene polymerizations to produce atactic polystyrene with high activities (up to 106 g polymer/(mol Ti·h)) and narrow polydispersities. Previously recognized CGCTiMe2 systems having marginal styrene homopolymerization activity are shown to be up to 3 orders of magnitude more active for styrene homopolymerization upon addition of organosilane.",

author = "Amin, {Smruti B.} and Marks, {Tobin J.}",

year = "2007",

month = jun

day = "4",

doi = "10.1021/om0700260",

language = "English",

volume = "26",

pages = "2960--2963",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "12",

}

TY - JOUR

T1 - Organosilane effects on organotitanium-catalyzed styrene polymerization

AU - Amin, Smruti B.

AU - Marks, Tobin J.

PY - 2007/6/4

Y1 - 2007/6/4

N2 - Organosilane reagents are introduced into organotitanium-mediated styrene polymerizations to produce atactic polystyrene with high activities (up to 106 g polymer/(mol Ti·h)) and narrow polydispersities. Previously recognized CGCTiMe2 systems having marginal styrene homopolymerization activity are shown to be up to 3 orders of magnitude more active for styrene homopolymerization upon addition of organosilane.

AB - Organosilane reagents are introduced into organotitanium-mediated styrene polymerizations to produce atactic polystyrene with high activities (up to 106 g polymer/(mol Ti·h)) and narrow polydispersities. Previously recognized CGCTiMe2 systems having marginal styrene homopolymerization activity are shown to be up to 3 orders of magnitude more active for styrene homopolymerization upon addition of organosilane.

UR - http://www.scopus.com/inward/record.url?scp=34250736685&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=34250736685&partnerID=8YFLogxK

U2 - 10.1021/om0700260

DO - 10.1021/om0700260

M3 - Article

AN - SCOPUS:34250736685

VL - 26

SP - 2960

EP - 2963

JO - Organometallics

JF - Organometallics

SN - 0276-7333

IS - 12

ER -

Access to Document

10.1021/om0700260