Organosilane effects on organotitanium-catalyzed styrene polymerization

Smruti B. Amin, Tobin J Marks

Research output: Contribution to journal › Article

12 Citations (Scopus)

Abstract

Organosilane reagents are introduced into organotitanium-mediated styrene polymerizations to produce atactic polystyrene with high activities (up to 106 g polymer/(mol Ti·h)) and narrow polydispersities. Previously recognized CGCTiMe2 systems having marginal styrene homopolymerization activity are shown to be up to 3 orders of magnitude more active for styrene homopolymerization upon addition of organosilane.

Original languageEnglish
Pages (from-to)2960-2963
Number of pages4
JournalOrganometallics
Volume26
Issue number12
DOIs
Publication statusPublished - Jun 4 2007

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Styrene
styrenes
polymerization
Polymerization
Homopolymerization
Polystyrenes
Polydispersity
reagents
polystyrene
Polymers
polymers

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry

Cite this

Organosilane effects on organotitanium-catalyzed styrene polymerization. / Amin, Smruti B.; Marks, Tobin J.

In: Organometallics, Vol. 26, No. 12, 04.06.2007, p. 2960-2963.

Research output: Contribution to journal › Article

Amin, SB & Marks, TJ 2007, 'Organosilane effects on organotitanium-catalyzed styrene polymerization', Organometallics, vol. 26, no. 12, pp. 2960-2963. https://doi.org/10.1021/om0700260
Amin SB, Marks TJ. Organosilane effects on organotitanium-catalyzed styrene polymerization. Organometallics. 2007 Jun 4;26(12):2960-2963. https://doi.org/10.1021/om0700260
Amin, Smruti B. ; Marks, Tobin J. / Organosilane effects on organotitanium-catalyzed styrene polymerization. In: Organometallics. 2007 ; Vol. 26, No. 12. pp. 2960-2963.
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