[Os2(CO)8(μ2-η2-C 2H4)] as a vibrational model for 1,2-di-σ chemisorbed ethylene on metal surfaces

Christopher E. Anson; Brian F.G. Johnson; Jack Lewis; Donald B. Powell; Norman Sheppard; Ashok K. Bhattacharyya; Bruce R. Bender; R. Morris Bullock; Robert T. Hembre; Jack R. Norton

doi:10.1039/C39890000703

[Os₂(CO)₈(μ₂-η²-C ₂H₄)] as a vibrational model for 1,2-di-σ chemisorbed ethylene on metal surfaces

Christopher E. Anson, Brian F.G. Johnson, Jack Lewis, Donald B. Powell, Norman Sheppard, Ashok K. Bhattacharyya, Bruce R. Bender, R. Morris Bullock, Robert T. Hembre, Jack R. Norton

Pacific Northwest National Laboratory

Research output: Contribution to journal › Article

23 Citations (Scopus)

Abstract

A vibrational assignment has been made for [Os₂(CO) ₈(μ₂-η²-C₂H₄)] and its deuteriated and ¹³C analogues: this complex is shown to be a vibrational model for molecular ethylene chemisorption, confirming the (1,2-di-σ) bonding mode.

Original language	English
Pages (from-to)	703-705
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	11
DOIs	https://doi.org/10.1039/C39890000703
Publication status	Published - Jan 1 1989

ASJC Scopus subject areas

Molecular Medicine

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Anson, C. E., Johnson, B. F. G., Lewis, J., Powell, D. B., Sheppard, N., Bhattacharyya, A. K., Bender, B. R., Bullock, R. M., Hembre, R. T., & Norton, J. R. (1989). [Os₂(CO)₈(μ₂-η²-C ₂H₄)] as a vibrational model for 1,2-di-σ chemisorbed ethylene on metal surfaces. Journal of the Chemical Society, Chemical Communications, (11), 703-705. https://doi.org/10.1039/C39890000703

[Os₂(CO)₈(μ₂-η²-C ₂H₄)] as a vibrational model for 1,2-di-σ chemisorbed ethylene on metal surfaces. / Anson, Christopher E.; Johnson, Brian F.G.; Lewis, Jack; Powell, Donald B.; Sheppard, Norman; Bhattacharyya, Ashok K.; Bender, Bruce R.; Bullock, R. Morris; Hembre, Robert T.; Norton, Jack R.

In: Journal of the Chemical Society, Chemical Communications, No. 11, 01.01.1989, p. 703-705.

Research output: Contribution to journal › Article

Anson, Christopher E. ; Johnson, Brian F.G. ; Lewis, Jack ; Powell, Donald B. ; Sheppard, Norman ; Bhattacharyya, Ashok K. ; Bender, Bruce R. ; Bullock, R. Morris ; Hembre, Robert T. ; Norton, Jack R. / [Os₂(CO)₈(μ₂-η²-C ₂H₄)] as a vibrational model for 1,2-di-σ chemisorbed ethylene on metal surfaces. In: Journal of the Chemical Society, Chemical Communications. 1989 ; No. 11. pp. 703-705.

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abstract = "A vibrational assignment has been made for [Os2(CO) 8(μ2-η2-C2H4)] and its deuteriated and 13C analogues: this complex is shown to be a vibrational model for molecular ethylene chemisorption, confirming the (1,2-di-σ) bonding mode.",

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